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Fachzeitschriften

Chemistry – An Asian Journal

Chemistry – An Asian Journal

Front Cover: A Direct Route to Habiterpenol Synthesis Using Anticopalic Acid as a Chiral Pool Template (Chem. Asian J. 15/2025)

Artikel

Front Cover: A Direct Route to Habiterpenol Synthesis Using Anticopalic Acid as a Chiral Pool Template (Chem. Asian J. 15/2025)

von Sittisak Oekchuae et al.

· 28.08.2025

Front Cover: A Direct Route to Habiterpenol Synthesis Using Anticopalic Acid as a Chiral Pool Template (Chem. Asian J. 15/2025)

The front cover portrays an ancient temple, gently embraced by the roots of surrounding trees, symbolizing the harmonious relationship between nature and human creation. This idea is echoed in the foreground image, which features anticopalic acid, i...

Cover Feature: Sucrose‐Derived Functionalized Layer Carbon with Excellent Proton Conductive Properties (Chem. Asian J. 15/2025)

Artikel

Cover Feature: Sucrose‐Derived Functionalized Layer Carbon with Excellent Proton Conductive Properties (Chem. Asian J. 15/2025)

von Xinyao Liu et al.

· 28.08.2025

Cover Feature: Sucrose‐Derived Functionalized Layer Carbon with Excellent Proton Conductive Properties (Chem. Asian J. 15/2025)

Catalyst-aided carbonization of sucrose to produce functionalized layered carbon materials exhibiting excellent proton conductivity is reported. Structural control during synthesis and post-synthetic functionalization introduces abundant oxygenated ...

Development and Optimization of Resorbable Biomaterials and Advanced 3D Scaffold Fabrication Techniques for Tissue Engineering Application

Artikel

Development and Optimization of Resorbable Biomaterials and Advanced 3D Scaffold Fabrication Techniques for Tissue Engineering Application

von Mohamed Jalaludeen et al.

· 28.08.2025

Development and Optimization of Resorbable Biomaterials and Advanced 3D Scaffold Fabrication Techniques for Tissue Engineering Application

The image depicts the methodology involved in the development and assessment of biomaterial scaffolds for tissue engineering applications. It illustrates scaffold fabrication techniques, the implantation of host cells, modulation of the immune respo...

The Application of N‐Aryl Glycines and Their Analogues in Visible‐Light‐Promoted Photoredox Catalysis

Artikel

The Application of N‐Aryl Glycines and Their Analogues in Visible‐Light‐Promoted Photoredox Catalysis

von Jian Wei et al.

· 28.08.2025

The Application of N‐Aryl Glycines and Their Analogues in Visible‐Light‐Promoted Photoredox Catalysis

N-Aryl glycines and their analogues have been widely explored in visible-light-promoted photoredox reactions to install an aminomethyl moiety or construct various N-heterocycles under mild conditions. Recent advances in this field have been summariz...

Advancing Biomarker Detection with Peptide‐Integrated Fluorescent Probes

Artikel

Advancing Biomarker Detection with Peptide‐Integrated Fluorescent Probes

von Subhendu Adhikari et al.

· 28.08.2025

Advancing Biomarker Detection with Peptide‐Integrated Fluorescent Probes

Over the decades, peptide-integrated fluorescent probes have been extensively used for the detection of biomarkers due to their high biocompatibility and specific detection ability towards various biological systems and diseases. This review provide...

Wet Chemical Synthesis of Cu‐Based Alloys and Their Electrocatalytic Applications

Artikel

Wet Chemical Synthesis of Cu‐Based Alloys and Their Electrocatalytic Applications

von Hanyun Pan et al.

· 28.08.2025

Wet Chemical Synthesis of Cu‐Based Alloys and Their Electrocatalytic Applications

This review highlights recent advances in Cu-based alloys, with a particular emphasis on wet chemical synthesis strategies and their electrocatalytic applications. Abstract Cu-based alloys, which are known for their abundant electroactive sites a...

Heterogeneous Catalysts for Toluene Oxidation

Artikel

Heterogeneous Catalysts for Toluene Oxidation

von Zhen Su et al.

· 28.08.2025

Heterogeneous Catalysts for Toluene Oxidation

Heterogeneous catalysts with excellent stability and recyclability, were summarized for the C-H bond activation of toluene, which holds great significance for both academia and industry. Heterogeneous thermocatalysts, photocatalysts, and electrocata...

Contemporary Progress on Graphene/Graphene Derivatives‐Based Adsorbents and Photocatalysts for the Eradication of Organic Toxins: An Updated Overview

Artikel

Contemporary Progress on Graphene/Graphene Derivatives‐Based Adsorbents and Photocatalysts for the Eradication of Organic Toxins: An Updated Overview

von Soumalya Bhowmik et al.

· 28.08.2025

Contemporary Progress on Graphene/Graphene Derivatives‐Based Adsorbents and Photocatalysts for the Eradication of Organic Toxins: An Updated Overview

The present review ruminates on graphene and its derivatives for the removal of organic toxins, covering the synthetic protocol and properties. Furthermore, this review streamlined a perception of recent advances in organic pollutant removal, cataly...

Advancements in the Applications of Mono and Bimetallic Rhenium(I) Complexes in Anticancer Therapeutics, Bioimaging, and Biosensing

Artikel

Advancements in the Applications of Mono and Bimetallic Rhenium(I) Complexes in Anticancer Therapeutics, Bioimaging, and Biosensing

von Nivedya T et al.

· 28.08.2025

Advancements in the Applications of Mono and Bimetallic Rhenium(I) Complexes in Anticancer Therapeutics, Bioimaging, and Biosensing

Multifuctional Re(I) complexes have been demonstrated as versatile agents for cancer therapeutics and molecular sensing. Abstract This article explores the development of various Re(I) complexes, including monometallic, bimetallic, homobimetallic...

Photoredox‐catalyzed Divergent Defluorofunctionalizations of gem‐difluoroarylalkenes with Nucleophiles to Access α‐arylated Carboxylic Acids and its Derivatives

Artikel

Photoredox‐catalyzed Divergent Defluorofunctionalizations of gem‐difluoroarylalkenes with Nucleophiles to Access α‐arylated Carboxylic Acids and its Derivatives

von Ting‐Ting Miao et al.

· 28.08.2025

Photoredox‐catalyzed Divergent Defluorofunctionalizations of gem‐difluoroarylalkenes with Nucleophiles to Access α‐arylated Carboxylic Acids and its Derivatives

An operationally simple and transition-metal-free photocatalytic approach has been developed for divergent defluorofunctionalizations of gem-difluoroarylalkenes with nucleophiles to access valuable α-arylated carboxylic acids, esters, and amides, fe...

Gold Nanoparticles‐Based Colorimetric Assay for Cathepsin S Activity

Artikel

Gold Nanoparticles‐Based Colorimetric Assay for Cathepsin S Activity

von Xianghan Li et al.

· 28.08.2025

Gold Nanoparticles‐Based Colorimetric Assay for Cathepsin S Activity

We developed a gold nanoparticle (AuNP)-based colorimetric assay for measuring cathepsin S activity using specific peptides. Abstract Cathepsin S (CatS) is a lysosomal enzyme belonging to the papain family of cysteine proteases. Studies have demo...

$Theoretical Investigation of the Stabilities and Reactivities of AumCun${\rm Au}_m{\rm Cu}_n$ Metallic Clusters (m+n = 13)$

Artikel

Theoretical Investigation of the Stabilities and Reactivities of AumCun${\rm Au}_m{\rm Cu}_n$ Metallic Clusters (m+n = 13)

von Pradeep Kumar et al.

· 28.08.2025

$Theoretical Investigation of the Stabilities and Reactivities of AumCun${\rm Au}_m{\rm Cu}_n$ Metallic Clusters (m+n = 13)$

Systematic generation and characterization of the lowest-energy isomers of Au_mCu_n clusters (m+ n = 13) using genetic algorithm ABCluster and DFT calculations. Their geometric stability, electronic structure, and catalytic behavior—especially for O2$...

Construction of Highly Active Coral‐Like Co/Ni‐BTC Catalyst and Its Application in CO2‐to‐CO Conversion

Artikel

Construction of Highly Active Coral‐Like Co/Ni‐BTC Catalyst and Its Application in CO2‐to‐CO Conversion

von Shan Weng et al.

· 28.08.2025

Construction of Highly Active Coral‐Like Co/Ni‐BTC Catalyst and Its Application in CO2‐to‐CO Conversion

A series of monometal Ni-BTC and bimetallic Co/Ni-BTC-x were prepared for photocatalytic CO₂ reduction. Among these catalysts, the coral-like Co/Ni-BTC-2 catalyst has the highest catalytic activity, with a maximum CO generation rate of 7.392 mmol/g/...

A Direct Route to Habiterpenol Synthesis Using Anticopalic Acid as a Chiral Pool Template

Artikel

A Direct Route to Habiterpenol Synthesis Using Anticopalic Acid as a Chiral Pool Template

von Sittisak Oekchuae et al.

· 28.08.2025

A Direct Route to Habiterpenol Synthesis Using Anticopalic Acid as a Chiral Pool Template

The concise total synthesis of habiterpenol utilizing the highly abundant natural product, anticopalic acid, as a chiral pool starting material is presented. The synthesis was completed in 10 steps with a 17.3% overall yield. DFT calculations to int...

Sucrose‐Derived Functionalized Layer Carbon with Excellent Proton Conductive Properties

Artikel

Sucrose‐Derived Functionalized Layer Carbon with Excellent Proton Conductive Properties

von Xinyao Liu et al.

· 28.08.2025

Sucrose‐Derived Functionalized Layer Carbon with Excellent Proton Conductive Properties

We report the catalyst-aided carbonization of sucrose to produce functionalized layered carbon materials exhibiting excellent proton conductivity. Structural control during synthesis and post-synthetic functionalization introduces abundant oxygenate...

Sterically Directed Site‐ and Stereoselective O‐Glycosylation of tert‐Butyl Gentisate

Artikel

Sterically Directed Site‐ and Stereoselective O‐Glycosylation of tert‐Butyl Gentisate

von Tingting Wang et al.

· 28.08.2025

Sterically Directed Site‐ and Stereoselective O‐Glycosylation of tert‐Butyl Gentisate

A sterically directed site- and stereoselective O-glycosylation of of tert-butyl gensitate has been developed. The excellent site-selectivity originates from the large steric hindrance of tert-butyl group. This glycosylation protocol, in conjunction...

A Bisphosphate Ligand for Zn2+ Ion Detection and Co‐Crystallization with N‐Rich Organic Molecules

Artikel

A Bisphosphate Ligand for Zn2+ Ion Detection and Co‐Crystallization with N‐Rich Organic Molecules

von Shubham Kumar et al.

· 28.08.2025

A Bisphosphate Ligand for Zn2+ Ion Detection and Co‐Crystallization with N‐Rich Organic Molecules

A bisphosphate ligand (tmbiphH₄) has been engaged here for Zn²⁺ detection via AIEE-based fluorescence quenching and construction of stable cocrystals with N-rich organic molecules. The multi-functional nature of tmbiphH₄, showcasing its role as a fl...

Distal Heteroaryl Ipso‐Migration of Unactivated Alkenes via Cobalt/Photoredox‐Catalyzed Hydrogen/Deuterium Atom Transfer

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Distal Heteroaryl Ipso‐Migration of Unactivated Alkenes via Cobalt/Photoredox‐Catalyzed Hydrogen/Deuterium Atom Transfer

von Masaaki Yamashita et al.

· 28.08.2025

Distal Heteroaryl Ipso‐Migration of Unactivated Alkenes via Cobalt/Photoredox‐Catalyzed Hydrogen/Deuterium Atom Transfer

Distal heteroaryl migration of alkenyl alcohols initiated by a metal-hydride hydrogen atom transfer (MHAT) is described. The remote migration strategy provided access to heteroaryl-containing ketones at remote positions that are inaccessible through...

Rh(III)‐Catalyzed Dual C─H Annulation of Isoquinolones and 1,6‐Diynes: Access to Naphtho‐Fused Polycyclic Derivatives

Artikel

Rh(III)‐Catalyzed Dual C─H Annulation of Isoquinolones and 1,6‐Diynes: Access to Naphtho‐Fused Polycyclic Derivatives

von Muniganti Naveen et al.

· 28.08.2025

Rh(III)‐Catalyzed Dual C─H Annulation of Isoquinolones and 1,6‐Diynes: Access to Naphtho‐Fused Polycyclic Derivatives

We disclose herein a Rh(III)-catalyzed weakly co-ordinating inherent functional group assisted dual C─H annulation of isoquinolones with 1,6-diynes, enabling the rapid construction of naptho-fused polycyclic derivatives. Abstract Transition metal...

Metal–Organic Gels with Zirconium–Imidazolium Frameworks: A Versatile Platform for Eco‐Friendly Organic Synthesis

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Metal–Organic Gels with Zirconium–Imidazolium Frameworks: A Versatile Platform for Eco‐Friendly Organic Synthesis

von Yanira Pérez‐Almarcha et al.

· 28.08.2025

Metal–Organic Gels with Zirconium–Imidazolium Frameworks: A Versatile Platform for Eco‐Friendly Organic Synthesis

A zirconiumimidazolium metalorganic xerogel (Zr-bcmimCl) was synthesized via a simple gelation method. It showed high efficiency, selectivity, and reusability in esterification and transesterification, making it a promising catalyst for sustainable ...

Smartphone‐Assisted Film Fluorescent Sensor for Quantitative and Visual Detection of Fluoride Ions

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Smartphone‐Assisted Film Fluorescent Sensor for Quantitative and Visual Detection of Fluoride Ions

von Xinyu Ma et al.

· 28.08.2025

Smartphone‐Assisted Film Fluorescent Sensor for Quantitative and Visual Detection of Fluoride Ions

A portable film-based fluorescent sensor DIP@CP enables smartphone-assisted F⁻ visual detection in real samples via colorimetric and ratiometric fluorescent changes. Abstract Film-based fluorescent sensor DIP@CP was developed by incorporating the...

How Solvation Structures Define the Cryoprotection Efficiency of Ethylene Glycol

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How Solvation Structures Define the Cryoprotection Efficiency of Ethylene Glycol

von Sudeshna Samanta et al.

· 28.08.2025

How Solvation Structures Define the Cryoprotection Efficiency of Ethylene Glycol

The evolution of HB-networks across three regimes of X_EG is illustrated: (i) bulk-like water with a percolating HB network, (ii) a mixed HB phase balancing waterwater and EGwater interactions, and (iii) an EG-rich phase dominated by EG self-associat...

Reliable Photoswitching of Vesicle‐Like Structures Assembled from Twisted Azo Derivatives

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Reliable Photoswitching of Vesicle‐Like Structures Assembled from Twisted Azo Derivatives

von Pyae Thu et al.

· 28.08.2025

Reliable Photoswitching of Vesicle‐Like Structures Assembled from Twisted Azo Derivatives

To construct fluorescent vesicle-like structures showing reliable photoswitching capability, we designed a new type of sterically twisted trigonal compound by linking three carbazole-based azo arms to one central phenyl ring via esterification. A...

Tailoring Monofluoride Substitution in a 2D Copper Chloride Perovskite Showing Thermochromism and High‐Temperature Dielectric Switching

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Tailoring Monofluoride Substitution in a 2D Copper Chloride Perovskite Showing Thermochromism and High‐Temperature Dielectric Switching

von Qian‐Sheng Zhang et al.

· 28.08.2025

Tailoring Monofluoride Substitution in a 2D Copper Chloride Perovskite Showing Thermochromism and High‐Temperature Dielectric Switching

Monofluoride substitution modulates molecular symmetry in a 2D copper-based perovskite, inducing a reversible phase transition at 351 K and triggering dual dielectric switching and thermochromism. Abstract 2D hybrid perovskites with diversified s...

(R)‐ and (S)‐SbF3(C8H9NO3): Chiral Antimony‐Based Hybrid Materials with Enhanced Second‐Harmonic Generation and Birefringence

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(R)‐ and (S)‐SbF3(C8H9NO3): Chiral Antimony‐Based Hybrid Materials with Enhanced Second‐Harmonic Generation and Birefringence

von Seoyeon Choi et al.

· 28.08.2025

(R)‐ and (S)‐SbF3(C8H9NO3): Chiral Antimony‐Based Hybrid Materials with Enhanced Second‐Harmonic Generation and Birefringence

We report two chiral NCS compounds, (R)-Sb and (S)-Sb, featuring aligned Sb³⁺ lone pairs and hydrogen-bonded [SbOF₃] polyhedra with 4-hydroxyphenylglycine. These structures exhibit strong SHG (2.6 × KDP), a wide band gap (4.19 eV), and suitable bire...

m‐Pyrenisubporphyrins and Their BIII Complexes and Reduced Congeners

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m‐Pyrenisubporphyrins and Their BIII Complexes and Reduced Congeners

von Yi Wang et al.

· 28.08.2025

m‐Pyrenisubporphyrins and Their BIII Complexes and Reduced Congeners

m-Pyrenisubporphyrins were synthesized and converted to B^III complexes, from which oxygen-atom-inserted product was formed upon heating in the air. Reductions of m-pyrenisubporphyrin with p-tosylhydrazide and K₂CO₃ gave m-pyrenisubchlorin and m-pyre...

Radical and Redox Forms of Pyridyl Appended MB‐DIPYs

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Radical and Redox Forms of Pyridyl Appended MB‐DIPYs

von Dijo Prasannan et al.

· 28.08.2025

Radical and Redox Forms of Pyridyl Appended MB‐DIPYs

We present the properties of the first pyridyl-appended nickel(II) complex of Manitoba dipyrromethene. Axial coordination of Ni^II(MB-DIPY)s with TPP^F20Zn was studied using UV–vis and fluorescence spectroscopy. The electronic structures and spectrosc...

Iron Catalysts with Silyl‐NHC Chelate Ligands: Controlling Factors for Hydroboration vs. Dehydrogenative Borylation of Olefins

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Iron Catalysts with Silyl‐NHC Chelate Ligands: Controlling Factors for Hydroboration vs. Dehydrogenative Borylation of Olefins

von Nozomu Ishiwata et al.

· 28.08.2025

Iron Catalysts with Silyl‐NHC Chelate Ligands: Controlling Factors for Hydroboration vs. Dehydrogenative Borylation of Olefins

Silyl-NHC chelate iron complexes with various substituents on NHC were synthesized and demonstrated to be active catalysts for hydroboration and dehydrogenative borylation of olefins. The selectivity of these borylation reactions is significantly co...

Controlled Synthesis of Chlorophylls‐Cu Doped Guanine Crystals with Long‐Term Photothermal Stability and Its Application as Camouflage Materials

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Controlled Synthesis of Chlorophylls‐Cu Doped Guanine Crystals with Long‐Term Photothermal Stability and Its Application as Camouflage Materials

von Jingyan Hao et al.

· 28.08.2025

Controlled Synthesis of Chlorophylls‐Cu Doped Guanine Crystals with Long‐Term Photothermal Stability and Its Application as Camouflage Materials

A functional green camouflage biomimetic material based on chlorophyll derivative chlorophylls–Cu occluded into the crystal lattices of single crystalline anhydrous guanine microplates was designed, which exhibit high reflectivity and strong depolar...

Efficient Synthesis of 1,4‐Diazepines via Tf2O Promoted [5+2] Annulation of Ynamides with Imidazolidines

Artikel

Efficient Synthesis of 1,4‐Diazepines via Tf2O Promoted [5+2] Annulation of Ynamides with Imidazolidines

von Baoxin Zhang et al.

· 28.08.2025

Efficient Synthesis of 1,4‐Diazepines via Tf2O Promoted [5+2] Annulation of Ynamides with Imidazolidines

Efficient and Sustainable Strategy for the Synthesis of 1,4-Diazepines via [5 + 2] Annulation of Ynamides with Imidazolidines. Abstract A Tf₂O-promoted [5+2] annulation of imidazolidines with ynamides has been developed, providing an efficient an...

Rh/Cu‐Cocatalyzed Cascade Cyclization Between Azidobenzamides and Diazopyrazolones for Synthesis of Spiroquinazolinones

Artikel

Rh/Cu‐Cocatalyzed Cascade Cyclization Between Azidobenzamides and Diazopyrazolones for Synthesis of Spiroquinazolinones

von Yu‐Hang Mi et al.

· 28.08.2025

Rh/Cu‐Cocatalyzed Cascade Cyclization Between Azidobenzamides and Diazopyrazolones for Synthesis of Spiroquinazolinones

Abstract Cocatalyzed by Rh₂(Oct)₄ (10 mol%)/CuI (10 mol%) and BINAP (20 mol%) in 1,2-dichloroethane at 80 °C, the cascade cyclization between azidobenzamides and diazopyrazolones underwent readily and furnished spiroquinazolinones in reasonable...

A Small‐Molecule Fluorescent Probe Featuring an Iminophosphorane Linker for Sequential Detection of Sn2⁺ Ions and Water with Bioimaging Applications

Artikel

A Small‐Molecule Fluorescent Probe Featuring an Iminophosphorane Linker for Sequential Detection of Sn2⁺ Ions and Water with Bioimaging Applications

von Avijit Ghosh et al.

· 28.08.2025

A Small‐Molecule Fluorescent Probe Featuring an Iminophosphorane Linker for Sequential Detection of Sn2⁺ Ions and Water with Bioimaging Applications

A novel fluorescent probe, NAP-TPP, derived from 1,4-naphthalic anhydride with an iminophosphorane group, enables sequential detection of Sn²⁺ and moisture. It shows a clear fluorescence/colorimetric response upon Sn²⁺ binding and acts as a ratiomet...

Benzil‐Dihydrazone Based Bis‐Schiff Base Dual‐Sensor for Expeditious Colorimetric Detection of Ni2+ and Fluorometric Detection of Ag+: Environmental and Biological Applications

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Benzil‐Dihydrazone Based Bis‐Schiff Base Dual‐Sensor for Expeditious Colorimetric Detection of Ni2+ and Fluorometric Detection of Ag+: Environmental and Biological Applications

von Dishen Kumar et al.

· 28.08.2025

Benzil‐Dihydrazone Based Bis‐Schiff Base Dual‐Sensor for Expeditious Colorimetric Detection of Ni2+ and Fluorometric Detection of Ag+: Environmental and Biological Applications

A novel dual mode chemosensor L has been reported which can detect Ni²⁺ colorimetrically and Ag⁺ fluorometrically with limit of detections 3.0 × 10⁻⁷ M respectively. It is useful for detection of Ni²⁺ in environmental samples, and Ag⁺ in BSA protein...

Sulfonatocalixarene Promotes Drug Assembly Based on Supramolecular Host•–Guest Complexation in Aqueous Solution

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Sulfonatocalixarene Promotes Drug Assembly Based on Supramolecular Host•–Guest Complexation in Aqueous Solution

von Khaleel I.

· 28.08.2025

Sulfonatocalixarene Promotes Drug Assembly Based on Supramolecular Host•–Guest Complexation in Aqueous Solution

This work explores the design and characterization of supramolecular thermoresponsive-assemblies formed through the interaction of sulfonatocalix[n]arenes (SCXn) with three drug molecules — doxepin, desipramine, and promazine — in aqueous solution. ...

The α‐ Versus β‐Selenylation of Pyrroles

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The α‐ Versus β‐Selenylation of Pyrroles

von Evgeny O. et al.

· 28.08.2025

The α‐ Versus β‐Selenylation of Pyrroles

The iodine-mediated selenylation of pyrroles with organic diselenides is proposed as a simple method to prepare the α or β selenylated pyrroles. The α→β intramolecular rearrangement is catalyzed by the released HI, but is prevented by the addition o...

Photocatalytic Synthesis of Succinimides from Aza‐1,6‐Enynes

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Photocatalytic Synthesis of Succinimides from Aza‐1,6‐Enynes

von Shivam A. et al.

· 28.08.2025

Photocatalytic Synthesis of Succinimides from Aza‐1,6‐Enynes

An operationally simple protocol for the stereoselective synthesis of functionally and structurally diverse succinimides using readily accessible aza-1,6-enynes. The strategy relies on the use of visible-light-mediated photocatalysis with a readily ...

Chelation Numbers Differentiate Performances of Co(II) Macrocyclic Catalysts in Electro‐/Photocatalytic CO2 Reduction

Artikel

Chelation Numbers Differentiate Performances of Co(II) Macrocyclic Catalysts in Electro‐/Photocatalytic CO2 Reduction

von Weilu Zhang et al.

· 28.08.2025

Chelation Numbers Differentiate Performances of Co(II) Macrocyclic Catalysts in Electro‐/Photocatalytic CO2 Reduction

4 vs. 5: Mechanistic studies clarify the role of chelation number in the structure-activity relationship in CO₂ reduction catalyzed by pyridiyldiimine-functionalized cobalt macrocyclic catalysts. Abstract Mechanistic studies with characterizing c...

Development of NiCo2O4/rGO Nanocomposites for High Performance Supercapacitors

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Development of NiCo2O4/rGO Nanocomposites for High Performance Supercapacitors

von Komal Ali et al.

· 28.08.2025

Development of NiCo2O4/rGO Nanocomposites for High Performance Supercapacitors

XX XX Abstract Transition metal oxide nanocomposites featuring diverse structures have garnered significant attention in the realm of supercapacitors. This interest is attributed to their cost-effectiveness, high surface area, rapid transport of ...

Nickel Hydroxide/Carbon Dot Nanocomposites as Effective Antibacterial Agents

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Nickel Hydroxide/Carbon Dot Nanocomposites as Effective Antibacterial Agents

von Davida Briana et al.

· 28.08.2025

Nickel Hydroxide/Carbon Dot Nanocomposites as Effective Antibacterial Agents

Functionalization of carbon dots by Ni(OH)₂ colloids leads to a markedly enhanced photodynamic antimicrobial activity as compared to that of the Ni(OH)₂-free counterpart, due to ready generation of reactive oxygen species and damage to the bacterial...

Pushing Carbon Nanohoops to Dark Green by Inserting BODIPY Dye Into Cycloparaphenylene Scaffolds

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Pushing Carbon Nanohoops to Dark Green by Inserting BODIPY Dye Into Cycloparaphenylene Scaffolds

von Bing Yuan et al.

· 28.08.2025

Pushing Carbon Nanohoops to Dark Green by Inserting BODIPY Dye Into Cycloparaphenylene Scaffolds

We synthesized a series of carbon nanohoops, [n]CPP-BODIPY (n = 6, 7, and 9), by embedding boron dipyrromethene (BODIPY) dye into cycloparaphenylene scaffolds. Due to the unique size effect and intramolecular charge transfer (ICT) character within c...

Alternative Approach to Avoid Drug Resistance: Polyhedral Inorganic and Metallomacrobicyclic 3D‐Shaped Guests Strongly Binding to Allosteric Sites and/or Macromolecular Interfaces

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Alternative Approach to Avoid Drug Resistance: Polyhedral Inorganic and Metallomacrobicyclic 3D‐Shaped Guests Strongly Binding to Allosteric Sites and/or Macromolecular Interfaces

von Yan Z.

· 28.08.2025

Alternative Approach to Avoid Drug Resistance: Polyhedral Inorganic and Metallomacrobicyclic 3D‐Shaped Guests Strongly Binding to Allosteric Sites and/or Macromolecular Interfaces

Abiotic, absolutely artificial molecules of polyhedral inorganic and metallomacrobicyclic compounds are proposed as the rigid 3D-shaped platforms for the design of promising therapeutic agents binding to the allosteric sites and/or the macromolecula...

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1st Edition of the “International Conference on Fundamental and Advanced Research in Chemistry (FARC‐2024)”

Front Cover: Boosting Homogeneous Hydrogenation of CO2 via the Data‐Driven Approach (Chem. Asian J. 16/2025)

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Front Cover: Boosting Homogeneous Hydrogenation of CO2 via the Data‐Driven Approach (Chem. Asian J. 16/2025)

von Min Zhang et al.

· 28.08.2025

Front Cover: Boosting Homogeneous Hydrogenation of CO2 via the Data‐Driven Approach (Chem. Asian J. 16/2025)

The cover picture illustrates a novel data-driven approach to the hydrogenation of CO₂, providing unprecedented opportunities to enhance catalyst design and to optimize reactions. This innovative data-driven approach excels at identifying hidden des...

Asymmetric Synthesis of Propargylic and Allenic Silanes, Germanes, and Stannanes

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Asymmetric Synthesis of Propargylic and Allenic Silanes, Germanes, and Stannanes

von Hai Chang et al.

· 28.08.2025

Asymmetric Synthesis of Propargylic and Allenic Silanes, Germanes, and Stannanes

Organotetrel compounds are important reagents with broad applications in chemical industries and natural product synthesis. This review provides a summary of strategies for the synthesis of propargylic and allenic organotetrels in their enantioenric...

Overcoming the Challenges in Aqueous Zinc Metal Batteries: Underlying Issues and Mitigation Strategies

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Overcoming the Challenges in Aqueous Zinc Metal Batteries: Underlying Issues and Mitigation Strategies

von Arya A et al.

· 28.08.2025

Overcoming the Challenges in Aqueous Zinc Metal Batteries: Underlying Issues and Mitigation Strategies

Aqueous zinc metal batteries (AZMBs) are promising technology for low-cost and environmental-friendly safe grid-scale energy storage. Yet, challenges such as dendrite growth, hydrogen evolution, and corrosion prevent their practical application. Thi...

Production of High Tensile Strength Bio‐Based Carbon Fibers: Advances, Challenges, and Emerging Applications

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Production of High Tensile Strength Bio‐Based Carbon Fibers: Advances, Challenges, and Emerging Applications

von Ajay Sharma et al.

· 28.08.2025

Production of High Tensile Strength Bio‐Based Carbon Fibers: Advances, Challenges, and Emerging Applications

This review summarizes recent advances in the production of carbon fibers from various bio-based feedstocks following pre-treatment and ammoxidation, spinning, stabilization, carbonization, and graphitization. It also highlights the prospects and ch...

Green Revolution of Lithium‐Ion Batteries: Prospects, Challenges and Environmental Impact

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Green Revolution of Lithium‐Ion Batteries: Prospects, Challenges and Environmental Impact

von Zeshan Ali et al.

· 28.08.2025

Green Revolution of Lithium‐Ion Batteries: Prospects, Challenges and Environmental Impact

Lithium-ion batteries have emerged as market leaders in numerous sectors, including electronics, electric vehicles, and the integration of renewable energy sources. When compared to other rechargeable battery types, LIBs have a greater energy-to-vol...

Advances in Multichromophoric Metal‐Free FRET Macrocycles and 2D Metallacycles

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Advances in Multichromophoric Metal‐Free FRET Macrocycles and 2D Metallacycles

von Vidushi Gupta et al.

· 28.08.2025

Advances in Multichromophoric Metal‐Free FRET Macrocycles and 2D Metallacycles

The review focuses on the design and synthetic strategies and photophysical properties of multichromophoric Förster resonance energy transfer (FRET) macrocycles namely, metal-free covalent macrocycles and coordination-driven 2D metallacycles. The ap...

Tetrel Cyclic Polyene Dianions as Precursors for the Pyramidal Clusters and Multi‐Decker Sandwiches

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Tetrel Cyclic Polyene Dianions as Precursors for the Pyramidal Clusters and Multi‐Decker Sandwiches

von Vladimir Ya et al.

· 28.08.2025

Tetrel Cyclic Polyene Dianions as Precursors for the Pyramidal Clusters and Multi‐Decker Sandwiches

The synthesis of the cyclobutadiene dianion and cyclopentadiene dianion derivatives, as well as their application toward pyramidal clusters and multi-decker sandwiches, are discussed in this review. The preparation of both main group element and tra...

Boosting Homogeneous Hydrogenation of CO2 via the Data‐Driven Approach

Artikel

Boosting Homogeneous Hydrogenation of CO2 via the Data‐Driven Approach

von Min Zhang et al.

· 28.08.2025

Boosting Homogeneous Hydrogenation of CO2 via the Data‐Driven Approach

The catalytic hydrogenation of CO₂ to produce value-added chemicals represents an essential strategy for sustainable carbon utilization. However, the design a novel and robust Ru catalyst for this process remains inadequately addressed. This concept...

Microplastic Removal from Water Using Biomass‐Based Carbon: A Review of Recent Advances

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Microplastic Removal from Water Using Biomass‐Based Carbon: A Review of Recent Advances

von I. Ihsanullah et al.

· 28.08.2025

Microplastic Removal from Water Using Biomass‐Based Carbon: A Review of Recent Advances

This review explores the potential of biomass-derived carbon in removing MPs from water. Abstract Microplastics (MPs) have emerged as priority contaminants in aquatic environments in recent years. Growing public concern surrounds their environmen...

Covalent Organic Framework Membranes for Gas Separation: Pore Chemistry Perspective

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Covalent Organic Framework Membranes for Gas Separation: Pore Chemistry Perspective

von Hao Zhang et al.

· 28.08.2025

Covalent Organic Framework Membranes for Gas Separation: Pore Chemistry Perspective

The latest progress of covalent organic framework (COF) membranes is summarized. The concept of pore chemistry is introduced and various strategies are proposed for engineering of pore structures to improve gas separation of COF membranes. Typical g...

Anchoring Silver Ions onto Cysteine‐Derivatized Cellulose and Its Antibacterial Effect

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Anchoring Silver Ions onto Cysteine‐Derivatized Cellulose and Its Antibacterial Effect

von Shirisha Balda et al.

· 28.08.2025

Anchoring Silver Ions onto Cysteine‐Derivatized Cellulose and Its Antibacterial Effect

In this work, cellulose was derivatized with cysteine (Cys) using two approaches, with the dialdehyde cellulose (DAC) route enabling higher cysteine incorporation. The resulting DAC-Cys material exhibited superior silver adsorption capacity compared...

Synthesis, Structural Analysis, and Photocatalytic Evaluation of Fe3O4/SnO2:Pr3+ Nanocomposite Using Artocarpus heterophyllus L., for Dye and Pesticide Degradation

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Synthesis, Structural Analysis, and Photocatalytic Evaluation of Fe3O4/SnO2:Pr3+ Nanocomposite Using Artocarpus heterophyllus L., for Dye and Pesticide Degradation

von Brojendro Singh et al.

· 28.08.2025

Synthesis, Structural Analysis, and Photocatalytic Evaluation of Fe3O4/SnO2:Pr3+ Nanocomposite Using Artocarpus heterophyllus L., for Dye and Pesticide Degradation

Magnetically active praseodymium (Pr³⁺) doped SnO₂ photocatalyzes dye and pesticide degradation in visible light. Light absorption excites electrons from valence to conduction, leaving holes. Pr³⁺ ions trap electrons, reducing recombination and impr...

Construction of Four 3D Isostructural Rare Earth‐Tetrabromoterephthalate Frameworks with stp Topology: Synthesis, Crystal Structure, and CO2 Sorption Properties

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Construction of Four 3D Isostructural Rare Earth‐Tetrabromoterephthalate Frameworks with stp Topology: Synthesis, Crystal Structure, and CO2 Sorption Properties

von Suwadee Jiajaroen et al.

· 28.08.2025

Construction of Four 3D Isostructural Rare Earth‐Tetrabromoterephthalate Frameworks with stp Topology: Synthesis, Crystal Structure, and CO2 Sorption Properties

3D rare earth metal-organic frameworks involving tetrabromoterephthalate (Br₄tp) linkers with a stp topological network, [RE(Br₄tp)_1.5]∙3H₂O (RE-MOF; RE = Er, Tm, Yb, and Lu), were synthesized via the covalent bonding of geometrically compatible mol...

Dual‐Mode Ratiometric ESIPT Probes for Vapor‐Phase Detection of a Pulmonary Agent: Leveraging Machine Learning for High‐Precision Quantitative Analysis

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Dual‐Mode Ratiometric ESIPT Probes for Vapor‐Phase Detection of a Pulmonary Agent: Leveraging Machine Learning for High‐Precision Quantitative Analysis

von Animesh Pal et al.

· 28.08.2025

Dual‐Mode Ratiometric ESIPT Probes for Vapor‐Phase Detection of a Pulmonary Agent: Leveraging Machine Learning for High‐Precision Quantitative Analysis

Benzimidazole-based ESIPT probes have been developed toward dual-mode ratiometric sensing of a pulmonary agent, phosgene both in solution phase and solid state. Machine-learning based polynomial regression models (quadratic and cubic) demonstrated e...

Artikel

Efficient and Diastereoselective Syntheses of C‐6 Homologues of DMJ, DNJ Iminosugars

Effects of Bases on the Mechanism of Ag(I)‐Catalyzed Selectivity of CO2 Incorporation into Conjugated Ynones: A Computational Study

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Effects of Bases on the Mechanism of Ag(I)‐Catalyzed Selectivity of CO2 Incorporation into Conjugated Ynones: A Computational Study

von Binfang Yuan et al.

· 28.08.2025

Effects of Bases on the Mechanism of Ag(I)‐Catalyzed Selectivity of CO2 Incorporation into Conjugated Ynones: A Computational Study

DFT Study on origin of chemoselectivity and difference of bases in catalytic activity in Ag(I)/base-catalyzed CO₂ carboxylation and cyclization. Abstract The mechanisms of AgOAc-catalyzed CO₂ incorporation into conjugated ynones are studied using...

SadPhos Library: A Comprehensive Resource for Exploring Chiral Ligand Chemical Space

Artikel

SadPhos Library: A Comprehensive Resource for Exploring Chiral Ligand Chemical Space

von Shuang Yu

· 28.08.2025

SadPhos Library: A Comprehensive Resource for Exploring Chiral Ligand Chemical Space

SadPhos—chiral sulfinamide phosphine (III)—is a pivotal class of ligands in asymmetric catalysis. We compile a dataset of 890 SadPhos ligands and employ data-driven methods to explore their chemical space, recognize highly active ligands, and propos...

Nickel‐Catalyzed Regioselective Access to Dibenzo[b,e]Azepinones: Mechanistic Study, Docking, and Biophysical Exploration of Binding Interactions with Human Hemoglobin

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Nickel‐Catalyzed Regioselective Access to Dibenzo[b,e]Azepinones: Mechanistic Study, Docking, and Biophysical Exploration of Binding Interactions with Human Hemoglobin

von Sk Shamim et al.

· 28.08.2025

Nickel‐Catalyzed Regioselective Access to Dibenzo[b,e]Azepinones: Mechanistic Study, Docking, and Biophysical Exploration of Binding Interactions with Human Hemoglobin

Nickel-catalyzed regioselective intramolecular acetylene hydroarylation process has been developed to produce dibenzo[b,e]azepin-6-one derivatives efficiently. DFT calculations are done to investigate the mechanistic pathway and one of the molecules...

Carboxymethyl Chitosan Delaminated Ti3C2 MXenes as a Potential Therapeutic Nano Platform to Combat Chronic Wounds

Artikel

Carboxymethyl Chitosan Delaminated Ti3C2 MXenes as a Potential Therapeutic Nano Platform to Combat Chronic Wounds

von Devendra Tiwari et al.

· 28.08.2025

Carboxymethyl Chitosan Delaminated Ti3C2 MXenes as a Potential Therapeutic Nano Platform to Combat Chronic Wounds

Schematic representation of CMC-delaminated MXene and its potential application in wound healing. Abstract The present study introduces carboxymethyl chitosan (CMC) delaminated Ti₃C₂ MXene (MX_CMC) as a novel therapeutic nanoplatform for chronic...

Multi‐Stimuli Responsive Tripodal Phenothiazine Derivatives and Their Applications in Monitoring Fish Spoilage, Anti‐counterfeiting Writing, and Visualization of Latent Fingerprints

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Multi‐Stimuli Responsive Tripodal Phenothiazine Derivatives and Their Applications in Monitoring Fish Spoilage, Anti‐counterfeiting Writing, and Visualization of Latent Fingerprints

von Ritika Sharma et al.

· 28.08.2025

Multi‐Stimuli Responsive Tripodal Phenothiazine Derivatives and Their Applications in Monitoring Fish Spoilage, Anti‐counterfeiting Writing, and Visualization of Latent Fingerprints

Tripodal phenothiazine-based donor-acceptor type, multi-stimuli responsive derivatives displaying solvatochromism, aggregation-induced emission enhancement, and reversible acidochromism were synthesized. These act as probes for moisture and amine, s...

Oxime‐Ether Group Transfer to Unpolarized C(sp3)─H Bonds via Light‐Induced HAT Catalysis

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Oxime‐Ether Group Transfer to Unpolarized C(sp3)─H Bonds via Light‐Induced HAT Catalysis

von Jayanta Dey et al.

· 28.08.2025

Oxime‐Ether Group Transfer to Unpolarized C(sp3)─H Bonds via Light‐Induced HAT Catalysis

This study introduces a sustainable and efficient method for direct alkane to oxime-ether functionalization via light-induced hydrogen-atom transfer (HAT) catalysis. Featuring low catalyst loadings, broad substrate scope, sunlight compatibility, and...

Carbene‐Catalyzed Asymmetric Acetalization to Access Chiral 3‐Aryloxyphthalides

Artikel

Carbene‐Catalyzed Asymmetric Acetalization to Access Chiral 3‐Aryloxyphthalides

von Chengli Mou et al.

· 28.08.2025

Carbene‐Catalyzed Asymmetric Acetalization to Access Chiral 3‐Aryloxyphthalides

A novel N-heterocyclic carbene (NHC)-catalyzed enantioselective synthesis of aryloxyphthalides from phthalaldehyde and phenols were developed with broad substrate scope, providing up to 98% enantioselectivity with excellent yields. This strategy off...

A Universal Platform for the In Situ Construction of Metal Nanoparticle‐Integrated Microdisk Array Electrodes Based on a Microcontact Printing Technique

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A Universal Platform for the In Situ Construction of Metal Nanoparticle‐Integrated Microdisk Array Electrodes Based on a Microcontact Printing Technique

von Yaojin Xu et al.

· 28.08.2025

A Universal Platform for the In Situ Construction of Metal Nanoparticle‐Integrated Microdisk Array Electrodes Based on a Microcontact Printing Technique

We developed a simple and versatile method to fabricate metal nanoparticle-integrated microelectrode arrays via in situ reduction on polydopamine microarrays patterned by microcontact printing. The resulting AuNPs array sensor exhibited significantl...

Embossing Redox‐Active Nickel(II) Complexes on Pencil Graphite Electrodes for Frugal Electrocatalytic Hydrogen Production

Artikel

Embossing Redox‐Active Nickel(II) Complexes on Pencil Graphite Electrodes for Frugal Electrocatalytic Hydrogen Production

von Sangharaj Diyali et al.

· 28.08.2025

Embossing Redox‐Active Nickel(II) Complexes on Pencil Graphite Electrodes for Frugal Electrocatalytic Hydrogen Production

This study transforms a simple pencil into a cost-effective graphite electrode, enhanced with nickel(II) complexes Ni-L^Me and Ni-L^Ph for efficient hydrogen production. Ni-L^Ph shows superior electrocatalytic activity and durability, driven by strong ...

Thioester Synthesis From Aldehydes and Its Derivatization to New C─O and C─N Bonds

Artikel

Thioester Synthesis From Aldehydes and Its Derivatization to New C─O and C─N Bonds

von Ankush Gupta et al.

· 28.08.2025

Thioester Synthesis From Aldehydes and Its Derivatization to New C─O and C─N Bonds

A benign approach for the thioesterification of aldehydes to novel thioesters has been achieved in a water-mediated condition. Exploring thioester for direct esterification and amidation findings that are simple and use readily available substrates ...

Sulfur‐Mediated Ring‐Opening Cyclization of Spirocyclopropanes for the Construction of Benzo[b]thiophene Skeleton

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Sulfur‐Mediated Ring‐Opening Cyclization of Spirocyclopropanes for the Construction of Benzo[b]thiophene Skeleton

von Hisanori Nambu et al.

· 28.08.2025

Sulfur‐Mediated Ring‐Opening Cyclization of Spirocyclopropanes for the Construction of Benzo[b]thiophene Skeleton

Regioselective ring-opening cyclization of spirocyclopropanes with NaSH proceeded smoothly, and subsequent addition of an acid afforded tetrahydrobenzo[b]thiophen-4-ones that could be converted into the 4-hydroxybenzo[b]thiophenes. This protocol pro...

Modified ISFET for Real‐Time Calcium Ion Sensing in MDA‐MB‐231 Breast Cancer Cells

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Modified ISFET for Real‐Time Calcium Ion Sensing in MDA‐MB‐231 Breast Cancer Cells

von Chinnawich Phamornnak et al.

· 28.08.2025

Modified ISFET for Real‐Time Calcium Ion Sensing in MDA‐MB‐231 Breast Cancer Cells

The Ca²⁺-FET device detects Ca²⁺ concentrations associated with MDA-MB-231 cell activities, such as proliferation, apoptosis, and Ca²⁺ fluctuation. The technique demonstrates the implementation of the ISFET for label-free and real-time ion monitorin...

Computational Access to 1,3,5,6,7‐Pentanitro‐3,6,7‐Triazabicyclo‐[3.1.1]‐Heptane (UIX): A Powerful Potential Explosive with Zero Oxygen Balance

Artikel

Computational Access to 1,3,5,6,7‐Pentanitro‐3,6,7‐Triazabicyclo‐[3.1.1]‐Heptane (UIX): A Powerful Potential Explosive with Zero Oxygen Balance

von Sohan Lal et al.

· 28.08.2025

Computational Access to 1,3,5,6,7‐Pentanitro‐3,6,7‐Triazabicyclo‐[3.1.1]‐Heptane (UIX): A Powerful Potential Explosive with Zero Oxygen Balance

A highly dense energetic cage nitramine (UIX) with zero oxygen balance was designed and investigated theoretically in search of excellent propellant formulations and explosive material, UIX has better energetic efficiency than RDX, HMX and comparabl...

N‐Confused Porphyrin as a Highly Active Ligand Scaffold for Molecular Catalysts of CO2 Reduction

Artikel

N‐Confused Porphyrin as a Highly Active Ligand Scaffold for Molecular Catalysts of CO2 Reduction

von Tong Zhou et al.

· 28.08.2025

N‐Confused Porphyrin as a Highly Active Ligand Scaffold for Molecular Catalysts of CO2 Reduction

Abstract Key to CO₂ reduction transformation is the development of catalysts that efficiently activate inert CO₂ molecules, enabling rapid reaction kinetics with minimal energy inputs. In this study, we introduce N-confused porphyrin (NCP) as a...

CO2‐Switchable Foams for Enhanced Oil Recovery and Carbon Sequestration

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CO2‐Switchable Foams for Enhanced Oil Recovery and Carbon Sequestration

von Zhaocheng Qian et al.

· 28.08.2025

CO2‐Switchable Foams for Enhanced Oil Recovery and Carbon Sequestration

CO₂ aqueous foams stabilized by a responsive surfactant, N-erucamido propyl-N,N-dimethylamine demonstrate switchable foaming behaviors under high-pressure and high-temperature conditions, in situ generation in porous media, improved mobility control...

Application of Ruthenium and Palladium Supported on Copper Materials in Selective Synthesis of N‐Benzylanilinyl‐Benzoimidazole and Benzoimidazoquinazoline Derivatives

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Application of Ruthenium and Palladium Supported on Copper Materials in Selective Synthesis of N‐Benzylanilinyl‐Benzoimidazole and Benzoimidazoquinazoline Derivatives

von Xiaoyong Chen et al.

· 28.08.2025

Application of Ruthenium and Palladium Supported on Copper Materials in Selective Synthesis of N‐Benzylanilinyl‐Benzoimidazole and Benzoimidazoquinazoline Derivatives

Loadable copper coordination polymers catalyze the green synthesis of benzimidazole derivatives. Abstract A novel nitrogen-containing carboxylic acid ligand was meticulously designed and synthesized. This ligand was subsequently employed to fabri...

In Vitro and In Live‐Cell Rapid Hydrazine Detection by Disaggregation of the AIEgen Microstructure

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In Vitro and In Live‐Cell Rapid Hydrazine Detection by Disaggregation of the AIEgen Microstructure

von Surajit Singh et al.

· 28.08.2025

In Vitro and In Live‐Cell Rapid Hydrazine Detection by Disaggregation of the AIEgen Microstructure

This study highlights the design and synthesis of AIEgens that exhibited excellent hydrazine detection in liquid and vapor phases and in live cell, with an impressive limit of 0.054 μμ by fluorescence turn on driven by hydrogen bonding and disaggreg...

Spectroscopic Characterization of Hydrogen‐Bonded 2,7‐Diazaindole‐Ammonia Complex: Laser Spectroscopic Investigations of Isolated Gas Phase Molecules

Artikel

Spectroscopic Characterization of Hydrogen‐Bonded 2,7‐Diazaindole‐Ammonia Complex: Laser Spectroscopic Investigations of Isolated Gas Phase Molecules

von Simran Baweja et al.

· 28.08.2025

Spectroscopic Characterization of Hydrogen‐Bonded 2,7‐Diazaindole‐Ammonia Complex: Laser Spectroscopic Investigations of Isolated Gas Phase Molecules

Abstract We present the vibrationally resolved two-color resonant two-photon ionization (R2PI), laser induced fluorescence (LIF), single vibronic level fluorescence (SVLF), and isomer-selective fluorescence dip infrared spectroscopy (FDIR) of 2...

Thioacetohydrazide‐Cored Dendritic Metallogels with Multi‐Stimuli‐Responsive and Adsorptive Properties

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Thioacetohydrazide‐Cored Dendritic Metallogels with Multi‐Stimuli‐Responsive and Adsorptive Properties

von Bo Jiang et al.

· 28.08.2025

Thioacetohydrazide‐Cored Dendritic Metallogels with Multi‐Stimuli‐Responsive and Adsorptive Properties

Core thioacetohydrazide-functionalized dendritic metallogelators have been designed and synthesized for constructing smart and adsorptive organogel materials. These dendritic organogels exhibited smart multiple stimulus-responsive behaviors and exce...

Imidazolyl Phosphine as Versatile Hemilabile Ligand: Synthesis and Characterization of a New Tetracationic Au20 Nanocluster

Artikel

Imidazolyl Phosphine as Versatile Hemilabile Ligand: Synthesis and Characterization of a New Tetracationic Au20 Nanocluster

von Wen‐Yan Liu et al.

· 28.08.2025

Imidazolyl Phosphine as Versatile Hemilabile Ligand: Synthesis and Characterization of a New Tetracationic Au20 Nanocluster

A new imidazolyl-phosphine-protected tetracationic Au₂₀ nanocluster has been readily synthesized, which underlines the potential of imidazolyl phosphine in the syntheses of hemilabile ligand-protected Au nanoclusters, and provides a new opportunity ...

Aggregation‐Free, Perylene‐Containing π‐Extended Kekulene with Improved Photoluminescence Quantum Yield

Artikel

Aggregation‐Free, Perylene‐Containing π‐Extended Kekulene with Improved Photoluminescence Quantum Yield

von Gui‐Fei Huo et al.

· 28.08.2025

Aggregation‐Free, Perylene‐Containing π‐Extended Kekulene with Improved Photoluminescence Quantum Yield

An aggregation-free, perylene-containing π-extended kekulene derivative 1 was synthesized and characterized, retaining frontier molecular orbitals similar to those of perylene and displaying high oscillator strengths, which together yield a fluoresc...

Visible Light‐Mediated Preparation of a Key Intermediate Employed in the Synthesis of Zolpidem and Several Analogs

Artikel

Visible Light‐Mediated Preparation of a Key Intermediate Employed in the Synthesis of Zolpidem and Several Analogs

von Ronei M. et al.

· 28.08.2025

Visible Light‐Mediated Preparation of a Key Intermediate Employed in the Synthesis of Zolpidem and Several Analogs

A new visible light-induced method is reported for the C3-alkylation of imidazo[1,2-a]pyrimidines and -pyridines with aryldiazoacetates. This protocol can be performed in open air and serves as a convenient entry to several known and new molecules. ...

Importance of the Number and Position of Tryptophan–Aspartate Repeats in Designing Peptide‐Based Membrane Fusion Inhibitors

Artikel

Importance of the Number and Position of Tryptophan–Aspartate Repeats in Designing Peptide‐Based Membrane Fusion Inhibitors

von Manbit Subhadarsi et al.

· 28.08.2025

Importance of the Number and Position of Tryptophan–Aspartate Repeats in Designing Peptide‐Based Membrane Fusion Inhibitors

To mitigate the challenge to design broad-spectrum entry inhibitors against enveloped viruses, we have designed WD-repeat containing peptides using coronin 1 as the template. We have further compared our recent results with other WD-peptides and elu...

Nanoaggregation‐Enhanced and Inverted Circularly Polarized Luminescence in Isomeric Schiff Base Bis(boron difluoride) Complexes

Artikel

Nanoaggregation‐Enhanced and Inverted Circularly Polarized Luminescence in Isomeric Schiff Base Bis(boron difluoride) Complexes

von Sipeng Wang et al.

· 28.08.2025

Nanoaggregation‐Enhanced and Inverted Circularly Polarized Luminescence in Isomeric Schiff Base Bis(boron difluoride) Complexes

Chiral V-shaped Schiff base molecules with positional isomerism were designed. Coordination with boron difluoride (BF₂) activated circularly polarized luminescence (CPL). Subsequent supramolecular nanoaggregation enabled precise CPL modulation. Nota...

Confined RuP2 Nanoparticles in N,P,S‐Tridoped Carbon as Superior Electrocatalyst for pH‐Wide Hydrogen Evolution

Artikel

Confined RuP2 Nanoparticles in N,P,S‐Tridoped Carbon as Superior Electrocatalyst for pH‐Wide Hydrogen Evolution

von Yu Sun et al.

· 28.08.2025

Confined RuP2 Nanoparticles in N,P,S‐Tridoped Carbon as Superior Electrocatalyst for pH‐Wide Hydrogen Evolution

This work explores a facile and effective method to prepare the highly active RuP₂ nanoparticles confined in N, P, S-codoped carbon, showing superior activity for the pH-wide HER along with good stability. Tridoped carbon can validly regulate the el...

Seven‐Coordinate Ruthenium Complex with an SiNN‐Pincer Ligand as a Catalyst for Vinyl C─H Deuteration of Olefins

Artikel

Seven‐Coordinate Ruthenium Complex with an SiNN‐Pincer Ligand as a Catalyst for Vinyl C─H Deuteration of Olefins

von Takashi Komuro et al.

· 28.08.2025

Seven‐Coordinate Ruthenium Complex with an SiNN‐Pincer Ligand as a Catalyst for Vinyl C─H Deuteration of Olefins

Seven-coordinate ruthenium complexes with an SiNN-pincer ligand were synthesized and used for catalytic deuteration reactions. All three vinyl C(sp²)─Hs of mono-substituted olefins were selectively deuterated in high deuterium ratio. Abstract Sev...

3‐Dicyanomethylene‐Substituted Thienothiophenes as the Terminal Units in Non‐Fullerene Electron Acceptor Molecules for Organic Photovoltaics

Artikel

3‐Dicyanomethylene‐Substituted Thienothiophenes as the Terminal Units in Non‐Fullerene Electron Acceptor Molecules for Organic Photovoltaics

von Kensuke Shibahashi et al.

· 28.08.2025

3‐Dicyanomethylene‐Substituted Thienothiophenes as the Terminal Units in Non‐Fullerene Electron Acceptor Molecules for Organic Photovoltaics

3-Dicyanomethylene thienothiophenes (CNTTs), a new series of electron acceptor units, were developed and incorporated into non-fullerene acceptors (NFAs). The CNTT-based NFAs exhibited favorable electronic structures and packing structures and thus ...

Cyclodextrin‐Assisted l‐Cysteine‐Capped Copper Nanoclusters: Rapid Synthesis, Enhanced Photoluminescence, and Small Molecule Interactions in Complex Biological Matrices

Artikel

Cyclodextrin‐Assisted l‐Cysteine‐Capped Copper Nanoclusters: Rapid Synthesis, Enhanced Photoluminescence, and Small Molecule Interactions in Complex Biological Matrices

von Kavya P. et al.

· 28.08.2025

Cyclodextrin‐Assisted l‐Cysteine‐Capped Copper Nanoclusters: Rapid Synthesis, Enhanced Photoluminescence, and Small Molecule Interactions in Complex Biological Matrices

In this report, we synthesized cysteine-capped copper nanoclusters (Cys-Cu NCs) in 30 min under ambient conditions. The inclusion of γ-Cyclodextrin (γ-CD) enhanced their stability and photoluminescence via aggregation-induced emission. The γ-CD-Cys-...

[5]Helicene‐Embedded Cycloparaphenylene Nanohoops with Möbius Topology: Synthesis, Photophysical Properties, and Aromaticity

Artikel

[5]Helicene‐Embedded Cycloparaphenylene Nanohoops with Möbius Topology: Synthesis, Photophysical Properties, and Aromaticity

von Huiji Yang et al.

· 28.08.2025

[5]Helicene‐Embedded Cycloparaphenylene Nanohoops with Möbius Topology: Synthesis, Photophysical Properties, and Aromaticity

Chiral [5]helicene-imbedded [7,8]CPPs are constructed. The Möbius nanohoops exhibit a significantly higher fluorescence quantum yields than pristine [5]helicene and [7,8]CPPs and, meanwhile, display moderately obvious Cotton effect and bright circul...

Tailoring Low‐Polarity Ionic Liquids Using Polyhedral Oligomeric Silsesquioxane (POSS) for Advanced Polymer Hybrids

Artikel

Tailoring Low‐Polarity Ionic Liquids Using Polyhedral Oligomeric Silsesquioxane (POSS) for Advanced Polymer Hybrids

von Aoi Watanabe et al.

· 28.08.2025

Tailoring Low‐Polarity Ionic Liquids Using Polyhedral Oligomeric Silsesquioxane (POSS) for Advanced Polymer Hybrids

The effects of the POSS core on the microenvironment around dyes in ionic liquids (ILs) were investigated through normalized polarity (E _T ^N) and Kamlet–Taft parameters with several types of solvatochromic dyes as a probe. Consequently, it was revea...

An Imidazole Functionalized Hf(IV) Metal–Organic Framework for Multi‐Component Biginelli and Hantzsch Condensation Reactions and Fluorometric Sensing of Anticancer Drug Raloxifene

Artikel

An Imidazole Functionalized Hf(IV) Metal–Organic Framework for Multi‐Component Biginelli and Hantzsch Condensation Reactions and Fluorometric Sensing of Anticancer Drug Raloxifene

von Sk Sakir et al.

· 28.08.2025

An Imidazole Functionalized Hf(IV) Metal–Organic Framework for Multi‐Component Biginelli and Hantzsch Condensation Reactions and Fluorometric Sensing of Anticancer Drug Raloxifene

Title: An Imidazole Functionalized Hf(IV) Metal–Organic Framework as Efficient Catalyst for Multi-Component Biginelli and Hantzsch Condensation Reactions and Fluorometric Sensing of an Anticancer Drug Raloxifene. Abstract The growing global popul...

A Versatile Disulfide‐Containing Solid‐Support Strategy for 3′‐Modifiers in Oligonucleotides: Introducing Modular Tandem Oligonucleotide Synthesis

Artikel

A Versatile Disulfide‐Containing Solid‐Support Strategy for 3′‐Modifiers in Oligonucleotides: Introducing Modular Tandem Oligonucleotide Synthesis

von Jagandeep S. et al.

· 28.08.2025

A Versatile Disulfide‐Containing Solid‐Support Strategy for 3′‐Modifiers in Oligonucleotides: Introducing Modular Tandem Oligonucleotide Synthesis

We report a versatile disulfide-containing linkage to solid support that enables on-column synthesis of DNA and RNA containing a 3′-amino or 3′-phosphate group. This orthogonal solid-support linker enables a protecting group strategy for the synthes...

Regulation of Defects in Carbon Nitride to Promote Photocatalytic Overall Water Splitting

Artikel

Regulation of Defects in Carbon Nitride to Promote Photocatalytic Overall Water Splitting

von Long Wang et al.

· 28.08.2025

Regulation of Defects in Carbon Nitride to Promote Photocatalytic Overall Water Splitting

By rationally tailoring the “trade-off” carbon and nitrogen vacancy contents, an almost defect-free high crystalline PTI was achieved and produced considerable OWS activity and a record efficiency of 37.8%. Abstract Crystal defects widely exist i...

Organic Fluorophores for Studying Lipid Membrane Structures and Dynamics

Artikel

Organic Fluorophores for Studying Lipid Membrane Structures and Dynamics

von Ritu Kumari et al.

· 01.09.2025

Organic Fluorophores for Studying Lipid Membrane Structures and Dynamics

Biomembranes are dynamic boundaries important for cellular communications, with diverse lipid compositions influencing biological processes. Fluorescent tools, especially organic fluorophore-based probes, have advanced the study of membrane structur...

Phosphine‐Free NNN Pincer Supported Cu(II) Catalysts for Sustainable Multi‐Component Synthesis of Pyrazolines and Pyrimidines via Dehydrogenation of Renewable Primary Alcohols

Artikel

Phosphine‐Free NNN Pincer Supported Cu(II) Catalysts for Sustainable Multi‐Component Synthesis of Pyrazolines and Pyrimidines via Dehydrogenation of Renewable Primary Alcohols

von Prashant Kukreti et al.

· 01.09.2025

Phosphine‐Free NNN Pincer Supported Cu(II) Catalysts for Sustainable Multi‐Component Synthesis of Pyrazolines and Pyrimidines via Dehydrogenation of Renewable Primary Alcohols

Herein, we present the first NNN pincer bis-imino pyridine-supported copper(II) catalysts for sustainable, eco-friendly, and practical multicomponent synthesis (MCS) of 1,3,5-trisubstituted pyrazolines (TriPyz) and 2,4,6-trisubstituted pyrimidines (...

CBr4 as an Efficient Halogen Bond Donor Catalyst in Pictet–Spengler Cyclizations: A Metal‐Free Approach to the Synthesis of Benzazepinoindoles and Tetrahydro‐β‐carbolines

Artikel

CBr4 as an Efficient Halogen Bond Donor Catalyst in Pictet–Spengler Cyclizations: A Metal‐Free Approach to the Synthesis of Benzazepinoindoles and Tetrahydro‐β‐carbolines

von Gokulprasanth Nataraj et al.

· 01.09.2025

CBr4 as an Efficient Halogen Bond Donor Catalyst in Pictet–Spengler Cyclizations: A Metal‐Free Approach to the Synthesis of Benzazepinoindoles and Tetrahydro‐β‐carbolines

This study introduces CBr₄ as the first organocatalyst for the Pictet–Spengler cyclization, enabling the efficient synthesis of diverse indole-based frameworks, including spirobenzazepinoindoles, tetrahydrobenzazepinoindoles, and tetrahydro-β-carbol...

Stimuli‐Responsive Supramolecular Polymers of Mono‐ and Bis‐triazolylphenylazoaniline‐Functionalized Copillar[5]Arenes: With Distinctive Binding Modes

Artikel

Stimuli‐Responsive Supramolecular Polymers of Mono‐ and Bis‐triazolylphenylazoaniline‐Functionalized Copillar[5]Arenes: With Distinctive Binding Modes

von Chun‐Yi Yao et al.

· 31.08.2025

Stimuli‐Responsive Supramolecular Polymers of Mono‐ and Bis‐triazolylphenylazoaniline‐Functionalized Copillar[5]Arenes: With Distinctive Binding Modes

Mono- and bis-functionalized copillar[5]arenes 1 and 2 form pH- and photo-responsive supramolecular polymers. Protonation of 1 enhances polymerization (1-H), differing from neutral 2, which forms a 1:1 complex with DMP5 via cavity binding. Polymeriz...

From Inception to Innovation: 20 Years of Nanoarchitectonics

Artikel

From Inception to Innovation: 20 Years of Nanoarchitectonics

von Katsuhiko Ariga et al.

· 31.08.2025

From Inception to Innovation: 20 Years of Nanoarchitectonics

Although nanotechnology was founded in the 20th century, the term nanoarchitectonics was first coined at the turn of the 21st century. Therefore, nanoarchitectonics has a history of about 20 years. In this review article, we will provide an overview...

Enantioselective Gram‐Scale Synthesis of Rasagiline via Chiral Phosphoric Acid‐Catalyzed Reduction of Cyclic Imine

Artikel

Enantioselective Gram‐Scale Synthesis of Rasagiline via Chiral Phosphoric Acid‐Catalyzed Reduction of Cyclic Imine

von Hayate Ishizuka et al.

· 31.08.2025

Enantioselective Gram‐Scale Synthesis of Rasagiline via Chiral Phosphoric Acid‐Catalyzed Reduction of Cyclic Imine

This study presents a practical and scalable enantioselective synthesis of rasagiline mesylate, a key Parkinson's disease drug, using asymmetric transfer hydrogenation of a challenging cyclic imine intermediate. By leveraging a chiral phosphoric aci...

Organocatalytic Regio‐ and Enantioselective Friedel‐Crafts Alkylation of N‐Aryl Anilines with Aurone‐Derived Azadienes: Access to Benzofuran Embedded Triarylmethanes

Artikel

Organocatalytic Regio‐ and Enantioselective Friedel‐Crafts Alkylation of N‐Aryl Anilines with Aurone‐Derived Azadienes: Access to Benzofuran Embedded Triarylmethanes

von Rupkumar Khuntia et al.

· 31.08.2025

Organocatalytic Regio‐ and Enantioselective Friedel‐Crafts Alkylation of N‐Aryl Anilines with Aurone‐Derived Azadienes: Access to Benzofuran Embedded Triarylmethanes

A catalytic asymmetric Friedel-Crafts alkylation of N-aryl anilines with aurone-derived azadienes for the first synthesis of benzofuran and N-aryl aniline containing triarylmethanes has been developed. Abstract Herein, we disclose a catalytic asy...

Electron‐Donor Functionalization at the N‐Position of Ethylenediamine Derivatives for Enhanced Aluminum Corrosion Inhibition

Artikel

Electron‐Donor Functionalization at the N‐Position of Ethylenediamine Derivatives for Enhanced Aluminum Corrosion Inhibition

von Huilian Liao et al.

· 31.08.2025

Electron‐Donor Functionalization at the N‐Position of Ethylenediamine Derivatives for Enhanced Aluminum Corrosion Inhibition

The action mechanism of ethylenediamine, tetramethylethylenediamine, and disodium ethylenediaminetetraacetic acid (EDTA-2Na) as corrosion inhibitors for aluminum radiators has been clarified, and the scientific laws between functional groups and cor...

Pd20Te7 Nanowires as an Efficient Multifunctional Catalyst for CO2 and O2 Electroreduction

Artikel

Pd20Te7 Nanowires as an Efficient Multifunctional Catalyst for CO2 and O2 Electroreduction

von Chenchen Li et al.

· 29.08.2025

Pd20Te7 Nanowires as an Efficient Multifunctional Catalyst for CO2 and O2 Electroreduction

Pd₂₀Te₇ nanowires (Pd₂₀Te₇ NWs) balance the adsorption of *COOH and *CO in the CO₂ reduction reaction and switch the O₂ adsorption mode in the oxygen reduction reaction from side-on to end-on. Consequently, Pd₂₀Te₇ NWs can be used as an efficient mu...

Recent Advances in the Synthesis of Bicyclo[4.1.0]Heptane Scaffolds

Artikel

Recent Advances in the Synthesis of Bicyclo[4.1.0]Heptane Scaffolds

von Jiguo Yang et al.

· 29.08.2025

Recent Advances in the Synthesis of Bicyclo[4.1.0]Heptane Scaffolds

Bicyclo[4.1.0]heptane derivatives have broad application prospects in the fields of biomedicine and agrochemistry. This review systematically summarizes the methods for constructing the bicyclo[4.1.0]heptane framework, based on two types of cyclizat...

Sustainable Mn‐Assisted Cu‐Catalyzed Cross‐Coupling of Primary Amides and Sulfonamides with (Hetero)Aryl and Styryl Halides: Investigating a Novel Catalytically Active Species

Artikel

Sustainable Mn‐Assisted Cu‐Catalyzed Cross‐Coupling of Primary Amides and Sulfonamides with (Hetero)Aryl and Styryl Halides: Investigating a Novel Catalytically Active Species

von Sampa Mondal et al.

· 28.08.2025

Sustainable Mn‐Assisted Cu‐Catalyzed Cross‐Coupling of Primary Amides and Sulfonamides with (Hetero)Aryl and Styryl Halides: Investigating a Novel Catalytically Active Species

Sustainable Mn-assisted Cu-catalyzed cross-coupling reaction has been developed for a range of (hetero)aryl, and styrenyl halides with various primary amides, sulfonamides, and cinnamamide, in air without solvents/added ligands. This protocol succes...

Titanium Oxynitride‐Supported Iridium Electrocatalysts for Efficient and Durable Acidic Oxygen Evolution Reaction

Artikel

Titanium Oxynitride‐Supported Iridium Electrocatalysts for Efficient and Durable Acidic Oxygen Evolution Reaction

von Jian Wei et al.

· 28.08.2025

Titanium Oxynitride‐Supported Iridium Electrocatalysts for Efficient and Durable Acidic Oxygen Evolution Reaction

Titanium oxynitride, a derivative of titanium nitride via controlled oxidation, is reported as a functional matrix for anchoring iridium (Ir) active species as an efficient OER electrocatalyst. Notably, with a low Ir loading of merely 33 wt.%, the c...

Investigating the Synergistic Influence of Redox‐Inactive Metal Ions at the Secondary Coordination Sphere of Non‐Heme Iron Complexes on Oxygen Reduction Reaction

Artikel

Investigating the Synergistic Influence of Redox‐Inactive Metal Ions at the Secondary Coordination Sphere of Non‐Heme Iron Complexes on Oxygen Reduction Reaction

von Aakash Santra et al.

· 28.08.2025

Investigating the Synergistic Influence of Redox‐Inactive Metal Ions at the Secondary Coordination Sphere of Non‐Heme Iron Complexes on Oxygen Reduction Reaction

The effect of different redox inactive metal ions embedded at the secondary coordination sphere (SCS) of non-heme iron(III) complexes has been examined toward the oxygen reduction reaction (ORR). The study discloses that Mg²⁺ and Ca²⁺ present at the...

Single‐Precursor Derived NCQDs from o‐Phenylenediamine as Fluorescent Sensors for Highly Selective and Sensitive Detection of Fe3⁺ Ions in Environmental Water Samples

Artikel

Single‐Precursor Derived NCQDs from o‐Phenylenediamine as Fluorescent Sensors for Highly Selective and Sensitive Detection of Fe3⁺ Ions in Environmental Water Samples

von Bushra Shaikh et al.

· 28.08.2025

Single‐Precursor Derived NCQDs from o‐Phenylenediamine as Fluorescent Sensors for Highly Selective and Sensitive Detection of Fe3⁺ Ions in Environmental Water Samples

NCQDs were synthesized via a simple one-step solvothermal method using o-phenylenediamine as single precursor. The NCQDs exhibit excellent fluorescence properties and serve as highly selective and sensitive fluorescent probes for Fe³⁺ ion detection ...

Influence of Ligand's Electronic Effect vs Temperature on Solvent Free Catalytic CO2 Fixation and Noncovalent Interactions in Molecular Architecture of Zn‐Complexes

Artikel

Influence of Ligand's Electronic Effect vs Temperature on Solvent Free Catalytic CO2 Fixation and Noncovalent Interactions in Molecular Architecture of Zn‐Complexes

von Anindita Das et al.

· 28.08.2025

Influence of Ligand's Electronic Effect vs Temperature on Solvent Free Catalytic CO2 Fixation and Noncovalent Interactions in Molecular Architecture of Zn‐Complexes

The electron-withdrawing effect of ligands showed an inverse relation with temperature dependency in the solvent-free catalysis of the selective transformation of CO₂ to cyclic carbonate by electronically varied Zn-complexes. Abstract A series of...

Interference of H2S During CO Detection by Probes Which Respond Through Tsuji–Trost Reaction—Does the Lack of Response Confirm Lack of Interference?

Artikel

Interference of H2S During CO Detection by Probes Which Respond Through Tsuji–Trost Reaction—Does the Lack of Response Confirm Lack of Interference?

von Archana Panthalattu et al.

· 28.08.2025

Interference of H2S During CO Detection by Probes Which Respond Through Tsuji–Trost Reaction—Does the Lack of Response Confirm Lack of Interference?

This study explores whether H₂S can influence the CO-releasing ability of CORM-3 or affect the generation of Pd(0) during the detection of CO by fluorescent probes that rely on the Tsuji–Trost reaction for activation. This was done using two differe...

Theoretical Insights into Enhanced Electrocatalytic Arsenic Oxidation on Au‐Decorated Pt Surfaces in Neutral Medium

Artikel

Theoretical Insights into Enhanced Electrocatalytic Arsenic Oxidation on Au‐Decorated Pt Surfaces in Neutral Medium

von Mohebul Ahsan et al.

· 28.08.2025

Theoretical Insights into Enhanced Electrocatalytic Arsenic Oxidation on Au‐Decorated Pt Surfaces in Neutral Medium

This study explores the electrocatalytic oxidation of arsenite on Au nanoparticle-decorated Pt surfaces in a neutral medium. DFT calculations showed stronger arsenite adsorption on Au-Pt (E _ads = − 2.045 eV) than on pure Au (−0.611 eV) or Pt (−0.769...

NiFe2O4@PEG Nanomaterials Mediated Synthesis of Functionalized Pyrroles via a Multi‐Component Reaction under Mild Conditions

Artikel

NiFe2O4@PEG Nanomaterials Mediated Synthesis of Functionalized Pyrroles via a Multi‐Component Reaction under Mild Conditions

von Babul Kalita et al.

· 28.08.2025

NiFe2O4@PEG Nanomaterials Mediated Synthesis of Functionalized Pyrroles via a Multi‐Component Reaction under Mild Conditions

Synthesis of NiFe₂O₄ nanoparticles (NPs) via the hydrothermal approach in the presence of poly(ethylene glycol) as a capping agent is reported to synthesize the functionalized pyrroles via a multi-component reaction. Abstract We report the synthe...

Dual‐Responsive Luminescent Iridium(III) Complex‐Based Sensors for Simultaneous and Selective Detection of Fluoride and Aluminium Ions

Artikel

Dual‐Responsive Luminescent Iridium(III) Complex‐Based Sensors for Simultaneous and Selective Detection of Fluoride and Aluminium Ions

von Sonali Bera et al.

· 28.08.2025

Dual‐Responsive Luminescent Iridium(III) Complex‐Based Sensors for Simultaneous and Selective Detection of Fluoride and Aluminium Ions

Luminescent iridium(III) complexes featuring cyclometalated 2-phenylbenzimidazole and bipyridine-based ancillary ligands were developed for the simultaneous and rapid detection of F⁻ and Al³⁺ ions in aqueous media. These probes exhibited excellent s...

A Yolk‐Shell Fe3O4/Pd@ZrO2 Catalyst with Space‐Confined Effect for Enhancing 4‐Nitrophenol Reduction

Artikel

A Yolk‐Shell Fe3O4/Pd@ZrO2 Catalyst with Space‐Confined Effect for Enhancing 4‐Nitrophenol Reduction

von Xiaojing Huang et al.

· 28.08.2025

A Yolk‐Shell Fe3O4/Pd@ZrO2 Catalyst with Space‐Confined Effect for Enhancing 4‐Nitrophenol Reduction

The 3D yolk-shell Fe3O4/Pd@ZrO2 catalyst with space-confined effect was developed via a vacuum-assisted strategy, which exhibited efficient and stable ability for 4-NP reduction under diverse water environments. Abstract Submicron catalysts with ...

Catalytic Reactions Involving the Oxidative Addition of Si─Halogen and Si─Pseudohalogen Bonds as a Key Step

Artikel

Catalytic Reactions Involving the Oxidative Addition of Si─Halogen and Si─Pseudohalogen Bonds as a Key Step

von Naoto Chatani

· 28.08.2025

Catalytic Reactions Involving the Oxidative Addition of Si─Halogen and Si─Pseudohalogen Bonds as a Key Step

This review highlights the transition metal-catalyzed reactions in which the oxidative addition of R₃Si-X (I, Br, Cl, F, and OTf) appears to be a key step. The reaction of C─C multiple bonds, such as alkenes, alkynes, and 1,3-dienes with R₃Si-X proc...

Total Syntheses of β‐Carboline‐Based Natural Alkaloids Including Secofascaplysin A, Strychnocarpine, Rutaecarpine and Euxylophoricine A Using NHC‐Catalyzed Imine Umpolung‒Oxidation

Artikel

Total Syntheses of β‐Carboline‐Based Natural Alkaloids Including Secofascaplysin A, Strychnocarpine, Rutaecarpine and Euxylophoricine A Using NHC‐Catalyzed Imine Umpolung‒Oxidation

von Killari Satyam et al.

· 28.08.2025

Total Syntheses of β‐Carboline‐Based Natural Alkaloids Including Secofascaplysin A, Strychnocarpine, Rutaecarpine and Euxylophoricine A Using NHC‐Catalyzed Imine Umpolung‒Oxidation

The total syntheses of the natural β-carboline alkaloids of marine/plant origin, including secofascaplysin A, strychnocarpine, rutaecarpine and euxylophoricine A have been accomplished using NHC-catalyzed imine umpolung‒oxidation as a key step. A...

Non‐Viral Gene Delivery Systems: Current Advances and Therapeutic Applications

Artikel

Non‐Viral Gene Delivery Systems: Current Advances and Therapeutic Applications

von Feifei Wang et al.

· 28.08.2025

Non‐Viral Gene Delivery Systems: Current Advances and Therapeutic Applications

This review systematically summarizes the recent progress in non-viral gene delivery systems, focus on their mechanistic studies for intracellular and extracellular gene delivery as well as the gene therapy applications. It also highlights the curre...

Synergy of Machine Learning and High‐Throughput Experimentation: A Road Toward Autonomous Synthesis

Artikel

Synergy of Machine Learning and High‐Throughput Experimentation: A Road Toward Autonomous Synthesis

von Rizvi Syed et al.

· 28.08.2025

Synergy of Machine Learning and High‐Throughput Experimentation: A Road Toward Autonomous Synthesis

Delve into the transformative synergy where high-throughput experimentation (HTE) produces rich datasets; machine learning (ML) enhances and speeds up discovery; and automated instrumentation are paving the way for self-sustaining research platforms...

A Light‐Up Fluorescent Probe for Detection of Reactive Oxygen Species and a Nerve Gas Simulant: Applications in Environmental, Cellular, and Vapor Phases

Artikel

A Light‐Up Fluorescent Probe for Detection of Reactive Oxygen Species and a Nerve Gas Simulant: Applications in Environmental, Cellular, and Vapor Phases

von Dipanjan Banik et al.

· 27.08.2025

A Light‐Up Fluorescent Probe for Detection of Reactive Oxygen Species and a Nerve Gas Simulant: Applications in Environmental, Cellular, and Vapor Phases

A hydrazinobenzothiazole-appended phenanthroimidazole-based turn-on fluorescent probe, TPIHB, was developed for dual-channel sensing of reactive oxygen species, hypochlorite, and nerve agent simulant diethyl chlorophosphate (DCP), through two distin...

Oxonium/Sulfonium Ylide Rearrangements to Access Chromenes and Thiochromenes: Concerted or Stepwise Pathway?

Artikel

Oxonium/Sulfonium Ylide Rearrangements to Access Chromenes and Thiochromenes: Concerted or Stepwise Pathway?

von Kajal B. et al.

· 27.08.2025

Oxonium/Sulfonium Ylide Rearrangements to Access Chromenes and Thiochromenes: Concerted or Stepwise Pathway?

Rhodium-catalyzed regio-divergent intramolecular rearrangements of diazo arylidene succinimide (DAS) derivatives have been achieved at room temperature to access bioactive chromene and thiochromene frameworks. Allyloxy and thioallyl-substituted DAS ...

Palladium‐Catalyzed Formal [3+2] Cycloadditions to Access Spirocyclopentane‐2‐oxindole Fused Chromanones, Quinolinones, and Thiochromones

Artikel

Palladium‐Catalyzed Formal [3+2] Cycloadditions to Access Spirocyclopentane‐2‐oxindole Fused Chromanones, Quinolinones, and Thiochromones

von Kiruthika Nachimuthu et al.

· 27.08.2025

Palladium‐Catalyzed Formal [3+2] Cycloadditions to Access Spirocyclopentane‐2‐oxindole Fused Chromanones, Quinolinones, and Thiochromones

Pd⁰-catalyzed [3+2] cycloaddition reaction between spirovinylcyclopropyl-2-oxindole and coumarin/bioisosteres is demonstrated. The simple combination of bpy/EtOH differentially influenced the yield up to 97% and diastereoselectivity up to > 99:1 ...

Breaking Down the Core Peptide of Amyloid Beta Protein with Enediyne and Mechanistic Study

Artikel

Breaking Down the Core Peptide of Amyloid Beta Protein with Enediyne and Mechanistic Study

von Meiling Tang et al.

· 27.08.2025

Breaking Down the Core Peptide of Amyloid Beta Protein with Enediyne and Mechanistic Study

A hydrogel model constructed from the Aβ core peptide was degraded using enediyne derivatives to validate their peptide cleavage capabilities through cycloaromatization. The radical mediated mechanism for backbone scission and modification was demon...

A “One‐to‐Multi” Activatable Near‐infrared Fluorescent Probe for the Sensitive Imaging of γ‑Glutamyl Transpeptidase Activity in Living Mice

Artikel

A “One‐to‐Multi” Activatable Near‐infrared Fluorescent Probe for the Sensitive Imaging of γ‑Glutamyl Transpeptidase Activity in Living Mice

von Yiru Ding et al.

· 13.08.2025

A “One‐to‐Multi” Activatable Near‐infrared Fluorescent Probe for the Sensitive Imaging of γ‑Glutamyl Transpeptidase Activity in Living Mice

An activatable near-infrared fluorogenic probe that elicits multiple effects—including covalent immobilization, fluorescence turn-on, and change in hydrophilicity and cell-permeability—upon a single interaction with γ-glutamyl transpeptidase, enabli...

A Review on MOFs as Efficient Fluorometric Chemosensors for Metal Ions

Artikel

A Review on MOFs as Efficient Fluorometric Chemosensors for Metal Ions

von Pritam Ghosh et al.

· 13.08.2025

A Review on MOFs as Efficient Fluorometric Chemosensors for Metal Ions

The review discusses the MOFs of transition, lanthanide, and alkaline earth metals that are widely used as chemosensors in the detection of different metal ions. Abstract MOFs are extensively utilized for recognizing metal ions. With their tunabl...

Increasing the Limits of Energy and Safety in Polynitro Tetrazoles by Incorporating Fluorine Atom

Artikel

Increasing the Limits of Energy and Safety in Polynitro Tetrazoles by Incorporating Fluorine Atom

von Jinghao Wu et al.

· 13.08.2025

Increasing the Limits of Energy and Safety in Polynitro Tetrazoles by Incorporating Fluorine Atom

In this paper, 2-(dinitromethyl)-5-(fluorodinitromethyl)-2H-tetrazole and its corresponding energetic salts were designed, synthesized through optimized routes, and thoroughly characterized. These compounds demonstrate high densities, positive entha...

Construction of Partially Amorphous CoNi‐LDH for Efficient Water Oxidation

Artikel

Construction of Partially Amorphous CoNi‐LDH for Efficient Water Oxidation

von Pengkun Wei et al.

· 13.08.2025

Construction of Partially Amorphous CoNi‐LDH for Efficient Water Oxidation

This work introduced an efficient method to synthesize a unique and inexpensive CoNi-LDH with high electrocatalytic activities, and it will be conductive to developing other catalysts toward OER. In addition, these excellent electrochemical performa...

Electroactive Foldamers Endowed with Tetrathiafulvalene Units: From Highly Stable Single Helical Structures to Redox‐Triggered Duplex Formation

Artikel

Electroactive Foldamers Endowed with Tetrathiafulvalene Units: From Highly Stable Single Helical Structures to Redox‐Triggered Duplex Formation

von Soussana Azar et al.

· 13.08.2025

Electroactive Foldamers Endowed with Tetrathiafulvalene Units: From Highly Stable Single Helical Structures to Redox‐Triggered Duplex Formation

Certain foldamers can form multiple helices, which is of interest in materials science, among other fields. By grafting tetrathiafulvalene units onto the ends of a helical oligomer, we report the synthesis and study of a foldamer that shows remarkab...

Fused Dithienoheterocycle‐Based Hole‐Transporting Materials for Efficient Perovskite Solar Cells

Artikel

Fused Dithienoheterocycle‐Based Hole‐Transporting Materials for Efficient Perovskite Solar Cells

von Kun‐Mu Lee et al.

· 13.08.2025

Fused Dithienoheterocycle‐Based Hole‐Transporting Materials for Efficient Perovskite Solar Cells

Two novel donor–acceptor–donor (D–A–D) structured small organic molecules with rigid and planar fused-heterocyclic cores for perovskite solar cells (PSCs) have been synthesized. The champion device in LK-2 exhibited a high power conversion efficienc...

Benzimidazole‐Based Dual‐State Luminophores with Acid Responsiveness and Thermo‐Switchable Emission in Phase‑Change Matrix

Artikel

Benzimidazole‐Based Dual‐State Luminophores with Acid Responsiveness and Thermo‐Switchable Emission in Phase‑Change Matrix

von Xueru Shan et al.

· 13.08.2025

Benzimidazole‐Based Dual‐State Luminophores with Acid Responsiveness and Thermo‐Switchable Emission in Phase‑Change Matrix

A series of benzimidazole-triphenylamine-based D–π–A compounds functionalized with flexible alkyl chains to achieve dual-state emission and acid/temperature-responsive luminescence. Abstract Dual-state luminescent materials, which emit strongly i...

Hypervalent Organotin(IV) Compounds as Efficient Catalysts for the Knoevenagel Condensation of Aldehydes

Artikel

Hypervalent Organotin(IV) Compounds as Efficient Catalysts for the Knoevenagel Condensation of Aldehydes

von Debayan Basu et al.

· 13.08.2025

Hypervalent Organotin(IV) Compounds as Efficient Catalysts for the Knoevenagel Condensation of Aldehydes

Hypervalent organotin(IV) catalyst: hypervalent organotin(IV) compounds show catalytic activity in the Knoevenagel condensation of aldehydes under mild reaction condition with a yield of product up to 97%. This study represents the first documented ...

Functional Nanomaterials Based Electrochemical and Chemiresistive Sensors for Hydrogen Detection: A Review

Artikel

Functional Nanomaterials Based Electrochemical and Chemiresistive Sensors for Hydrogen Detection: A Review

von Pushpesh Ranjan et al.

· 13.08.2025

Functional Nanomaterials Based Electrochemical and Chemiresistive Sensors for Hydrogen Detection: A Review

Carbon-based nanomaterials, semiconducting metal oxides, and metal nanoparticles based sensitive electrochemical and chemiresistive sensors for the detection of hydrogen are dicussed in this review. These sensors offer excellent detection performanc...

Chloroform‐Driven Excited‐State Protonation of Pyrene–Dialkylaniline Derivatives Under Visible Light

Artikel

Chloroform‐Driven Excited‐State Protonation of Pyrene–Dialkylaniline Derivatives Under Visible Light

von Kumar Dineshkumar et al.

· 13.08.2025

Chloroform‐Driven Excited‐State Protonation of Pyrene–Dialkylaniline Derivatives Under Visible Light

Reversible photochemistry of pyrene: a light-driven protonation of N,N-dialkylaniline substituted pyrene, uniquely facilitated by chloroform as a proton source, unfolds through intramolecular electron transfer (IET) and radical-mediated hydrogen abs...

Tuning Phase Stability and Band Gap in Vacancy‐Ordered Double Perovskites Rb(2‐x)CsxSnI6 Through Variations in A‐Site Cation

Artikel

Tuning Phase Stability and Band Gap in Vacancy‐Ordered Double Perovskites Rb(2‐x)CsxSnI6 Through Variations in A‐Site Cation

von R. Chandan et al.

· 13.08.2025

Tuning Phase Stability and Band Gap in Vacancy‐Ordered Double Perovskites Rb(2‐x)CsxSnI6 Through Variations in A‐Site Cation

Vacancy-ordered halide double perovskites Rb₂SnI₆, Rb_1.1Cs_0.9SnI₆, and Cs₂SnI₆ have been synthesized at room temperature. Rb₂SnI₆ and Rb_1.1Cs_0.9SnI₆ show temperature-induced structural changes―cubic (Fm3̅m) ⇌ tetragonal (P4/mnc) ⇌ monoclinic (P2₁/n)...

Influence of Crowder Geometry and Flexibility on Polymer Translocation Dynamics

Artikel

Influence of Crowder Geometry and Flexibility on Polymer Translocation Dynamics

von Akshay Chauhan et al.

· 13.08.2025

Influence of Crowder Geometry and Flexibility on Polymer Translocation Dynamics

We examine how the rigidity of rigid rod crowders affects polymer translocation through nanopores. By adjusting these crowders’ shape, length, and bending stiffness, we reveal significant changes in translocation time and probability, underscoring h...

A Practical Guide to Heterogeneous Catalysis in Hydrocarbon Transformations

Artikel

A Practical Guide to Heterogeneous Catalysis in Hydrocarbon Transformations

von Kelvin A. et al.

· 13.08.2025

A Practical Guide to Heterogeneous Catalysis in Hydrocarbon Transformations

A focused overview of the catalytic processing of hydrocarbons to transform them into more valuable compounds is presented. This work is intended to assist BSc, MSc, and PhD students, as well as junior researchers, in selecting and performing approp...

Heteroatom Doping, Defect Engineering, and Stability of Transition Metal Diselenides for Electrocatalytic Water Splitting

Artikel

Heteroatom Doping, Defect Engineering, and Stability of Transition Metal Diselenides for Electrocatalytic Water Splitting

von Riya Mudoi et al.

· 10.08.2025

Heteroatom Doping, Defect Engineering, and Stability of Transition Metal Diselenides for Electrocatalytic Water Splitting

This mini review provides a comprehensive overview on strategies to enhance the catalytic activity of transition metal diselenides for water electrolysis. The synergistic effect of heteroatom doping and defect engineering is explored, which is respo...

Design and Synthesis of Novel Nitrofurantoin Derivatives as Antibacterial Agents Against Acinetobacter Baumannii

Artikel

Design and Synthesis of Novel Nitrofurantoin Derivatives as Antibacterial Agents Against Acinetobacter Baumannii

von Han Deng et al.

· 10.08.2025

Design and Synthesis of Novel Nitrofurantoin Derivatives as Antibacterial Agents Against Acinetobacter Baumannii

Abstract Acinetobacter baumannii, identified by the World Health Organization (WHO) as one of the first batches of antibiotic-resistant bacteria in urgent need of new antibiotics, poses a great threat to global health. Nitrofurantoin is a kind ...

Artikel

RETRACTION: Nanoscale Zero‐Valent Iron Particles Supported on Reduced Graphene Oxides by Using a Plasma Technique and Their Application for Removal of Heavy‐Metal Ions

A Review on Metal–Organic Frameworks as Catalytic Material for Oxidation Reactions

Artikel

A Review on Metal–Organic Frameworks as Catalytic Material for Oxidation Reactions

von Monjuly Rongpipi et al.

· 10.08.2025

A Review on Metal–Organic Frameworks as Catalytic Material for Oxidation Reactions

Metal–organic frameworks (MOFs) serve as effective heterogeneous catalysts in organic oxidation reactions, including those of alkenes, alkanes, and alcohols. Their high surface area, structural tunability, and reusability make them promising alterna...

A Benzothiadiazole‐Based Thiourea Receptor for Selective Chloride Extraction and Reversible Fluoride Sensing

Artikel

A Benzothiadiazole‐Based Thiourea Receptor for Selective Chloride Extraction and Reversible Fluoride Sensing

von Iti Ghosh et al.

· 10.08.2025

A Benzothiadiazole‐Based Thiourea Receptor for Selective Chloride Extraction and Reversible Fluoride Sensing

A highly fluorescent receptor, BDTU, featuring a photoresponsive benzothiadiazole unit and HB donor thiourea motif, displays anion selectivity toward Cl⁻ over other halides and oxyanions, while a preliminary solid–liquid extraction experiment sugges...

Dimeric Co(II) Complexes as Excellent Electrocatalysts Toward Efficient Hydrogen and Oxygen Evolution Reactions and Electrochemical Water Splitting

Artikel

Dimeric Co(II) Complexes as Excellent Electrocatalysts Toward Efficient Hydrogen and Oxygen Evolution Reactions and Electrochemical Water Splitting

von Sanobar Naaz et al.

· 10.08.2025

Dimeric Co(II) Complexes as Excellent Electrocatalysts Toward Efficient Hydrogen and Oxygen Evolution Reactions and Electrochemical Water Splitting

In this study, two Co(II) dimeric complexes have been reported. Interestingly, the synthesized complexes exhibit significant electrochemical water splitting activity for hydrogen and oxygen evolution reactions (OER) in alkaline medium. However, chlo...

Transfer Hydrogenation Catalyzed by a Bifunctional Cobalt‐Based Supramolecular Complex Offering Hydrogen Bonding Cavities

Artikel

Transfer Hydrogenation Catalyzed by a Bifunctional Cobalt‐Based Supramolecular Complex Offering Hydrogen Bonding Cavities

von Divya Goyal et al.

· 10.08.2025

Transfer Hydrogenation Catalyzed by a Bifunctional Cobalt‐Based Supramolecular Complex Offering Hydrogen Bonding Cavities

A Co-containing supramolecular complex, offering both Lewis acidic–basic and Brønsted acidic sites, functions as a remarkable heterogeneous catalyst for promoting the base-free transfer hydrogenation of assorted carbonyl and imine substrates with hi...

Asymmetric Synthesis of Bioactive Molecules for Pesticide Development with N‐Heterocyclic Carbene (NHC)‐Organocatalysis

Artikel

Asymmetric Synthesis of Bioactive Molecules for Pesticide Development with N‐Heterocyclic Carbene (NHC)‐Organocatalysis

von Peng Chen et al.

· 09.08.2025

Asymmetric Synthesis of Bioactive Molecules for Pesticide Development with N‐Heterocyclic Carbene (NHC)‐Organocatalysis

NHC-catalyzed asymmetric synthesis of chiral antifungal, antibacterial, and antiviral active molecules. Abstract Chiral pesticides have gained significant attention in modern agrochemical research and development due to the distinct interactions ...

Behavior of Supramolecular Polymerization of Alkynylplatinum(II) Complex in Different Compositions of DMSO and Water

Artikel

Behavior of Supramolecular Polymerization of Alkynylplatinum(II) Complex in Different Compositions of DMSO and Water

von Minjoo Kim et al.

· 01.08.2025

Behavior of Supramolecular Polymerization of Alkynylplatinum(II) Complex in Different Compositions of DMSO and Water

The self-assembly of R-L-Pt-BP in DMSO/H₂O showed solvent-dependent CD and photoluminescence (PL). A cooperative mechanism with red-shifted emission and higher ΔG appeared in 2:8 mixtures; whereas 5:5 and 8:2 followed an isodesmic model with opposit...

Anion‐Induced Blue to Green Color Fluorogenicity inside a Fluorescent Room Temperature Ionic Liquid and Its Implication for the Construction of Molecular Logic Gates

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Anion‐Induced Blue to Green Color Fluorogenicity inside a Fluorescent Room Temperature Ionic Liquid and Its Implication for the Construction of Molecular Logic Gates

von Sabbir Ahamed et al.

· 01.08.2025

Anion‐Induced Blue to Green Color Fluorogenicity inside a Fluorescent Room Temperature Ionic Liquid and Its Implication for the Construction of Molecular Logic Gates

A blue-emitting room temperature ionic liquid, [TTP]⁺ ₃[HPTS]³ ⁻, has been introduced and utilized for cascade detection of fluoride (F⁻) and hydrogen bisulfate (HSO₄ ⁻) ions. Abstract A blue-emitting photoluminescent room temperature ionic l...

Cu‐Catalyzed Synthesis of Isoxazolidine/1,2‐Oxazinane‐3‐ylidene Sulfonamide from O‐Alkynyl Hydroxylamines: A Route to Sulfamethoxazole Analogues

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Cu‐Catalyzed Synthesis of Isoxazolidine/1,2‐Oxazinane‐3‐ylidene Sulfonamide from O‐Alkynyl Hydroxylamines: A Route to Sulfamethoxazole Analogues

von Santosh J. et al.

· 01.08.2025

Cu‐Catalyzed Synthesis of Isoxazolidine/1,2‐Oxazinane‐3‐ylidene Sulfonamide from O‐Alkynyl Hydroxylamines: A Route to Sulfamethoxazole Analogues

A copper-catalyzed cascade reaction involving CuAAC (copper-catalyzed azide–alkyne cycloaddition), ketenimine formation, and hydroamination of alkynyl hydroxylamines enables the synthesis of isoxazolidines and novel 1,2-oxazinane-3-ylidene sulfonami...

Recent Trends in Enzyme‐Based Biosensors for On‐Site Screening of Antibiotic Residues

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Recent Trends in Enzyme‐Based Biosensors for On‐Site Screening of Antibiotic Residues

von Sapna Sudan et al.

· 31.07.2025

Recent Trends in Enzyme‐Based Biosensors for On‐Site Screening of Antibiotic Residues

Antibiotic pollution pathways and biosensor intervention for effective monitoring and control of antimicrobial resistance. Abstract Antibiotics are used to treat both humans and animals for both preventive and therapeutic purposes. The overrelia...

Photoallylation Mechanism of Dicyanobenzenes with Allyltrimethylsilane in Solution Investigated by Cold UV and IR Spectroscopy in the Gas Phase

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Photoallylation Mechanism of Dicyanobenzenes with Allyltrimethylsilane in Solution Investigated by Cold UV and IR Spectroscopy in the Gas Phase

von Ryosuke Goda et al.

· 31.07.2025

Photoallylation Mechanism of Dicyanobenzenes with Allyltrimethylsilane in Solution Investigated by Cold UV and IR Spectroscopy in the Gas Phase

The structure of the chemical intermediate in photoallylation of dicyanobenzenes (DCBs) with allyltrimethylsilane (ATMS) in acetonitrile was determined by cold UV and IR spectroscopy in the gas phase. The reaction mechanism was discussed on the basi...

Tuning of Aromaticity in Meso‐Thienyl 22‐Oxabenzonorroles

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Tuning of Aromaticity in Meso‐Thienyl 22‐Oxabenzonorroles

von Jyoti Ranjan et al.

· 31.07.2025

Tuning of Aromaticity in Meso‐Thienyl 22‐Oxabenzonorroles

Meso-thienyl 22-oxabenzonorroles containing one to three thienyl groups at the meso-positions were synthesized over sequence of four simple steps in 11%–15% yields using readily available oxabenzobilanes as the key precursors. NMR, NICS, and AICD st...

Novel Amino Derivatives and Carboxamides of Chromen‐2‐one: Synthesis, Antimicrobial Activity, and Molecular Docking Studies

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Novel Amino Derivatives and Carboxamides of Chromen‐2‐one: Synthesis, Antimicrobial Activity, and Molecular Docking Studies

von Abha Kathuria et al.

· 31.07.2025

Novel Amino Derivatives and Carboxamides of Chromen‐2‐one: Synthesis, Antimicrobial Activity, and Molecular Docking Studies

Novel amino derivatives and carboxamides of chromen-2-one were synthesized and evaluated for antimicrobial activity. Compound 9 showed potent antifungal effects, while compounds 10 and 13 were active against the bacteria. Docking studies revealed st...

Competitive Photoinduced Energy and Electron Transfer in a Donor–Acceptor Triad Consisting of Zinc Porphyrin ‐ Bis‐Styryl‐BODIPY Dyad Coordinated to Fullerene

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Competitive Photoinduced Energy and Electron Transfer in a Donor–Acceptor Triad Consisting of Zinc Porphyrin ‐ Bis‐Styryl‐BODIPY Dyad Coordinated to Fullerene

von Ram Ratan et al.

· 30.07.2025

Competitive Photoinduced Energy and Electron Transfer in a Donor–Acceptor Triad Consisting of Zinc Porphyrin ‐ Bis‐Styryl‐BODIPY Dyad Coordinated to Fullerene

A newly synthesized and assembled supramolecular triad comprised of BODIPY, ZnP, and C₆₀ entities, probed competitive energy and electron transfer events upon photoexcitation using advanced theoretical and experimental methods. Mimicry of antenna-re...

Reactivity and Activation Barrier Origins of Heavy Isocyanide‐Like Molecules Featuring a Group 14═P Double Bond Toward Methyl Iodide: A Chemical Insight

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Reactivity and Activation Barrier Origins of Heavy Isocyanide‐Like Molecules Featuring a Group 14═P Double Bond Toward Methyl Iodide: A Chemical Insight

von Zheng‐Feng Zhang et al.

· 30.07.2025

Reactivity and Activation Barrier Origins of Heavy Isocyanide‐Like Molecules Featuring a Group 14═P Double Bond Toward Methyl Iodide: A Chemical Insight

Theoretical studies suggest that while heavy isocyanide analogs with Ge = P, Sn = P, and Pb = P groups are reactive toward CH₃I in an addition reaction, those with C = P or Si = P groups lack this reactivity. Abstract This study examines the reac...

Slow Magnetic Relaxation with High Energy Barrier in Kramer Nd (III) Dinuclear Complex

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Slow Magnetic Relaxation with High Energy Barrier in Kramer Nd (III) Dinuclear Complex

von Pradip Kumar et al.

· 29.07.2025

Slow Magnetic Relaxation with High Energy Barrier in Kramer Nd (III) Dinuclear Complex

A dinuclear Nd(III) molecule, which features a phenoxide bridged and axial symmetry Nd(III) ions, exhibits slow magnetic relaxation. It demonstrates the most significant phenomenological energy barrier among the Nd-dimers. The ab initio calculations...

Engineering Photolabile Cyclopentane‐Fused Coumarins: From One‐Pot Synthesis to Mechanistic Study for Visible Light‐Triggered Photolysis

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Engineering Photolabile Cyclopentane‐Fused Coumarins: From One‐Pot Synthesis to Mechanistic Study for Visible Light‐Triggered Photolysis

von Jau‐Tien Lin et al.

· 29.07.2025

Engineering Photolabile Cyclopentane‐Fused Coumarins: From One‐Pot Synthesis to Mechanistic Study for Visible Light‐Triggered Photolysis

Cyclopentane fusion in coumarin photocages transforms their behavior from rapid S_N1-mediated release (minutes) to a slower elimination pathway (hours), accompanied by dramatic spectral changes upon photolysis, providing complementary tools for contr...

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Intramolecular Halogen Bonds Assist in Activating Carbonyl Groups for the Catalytic Synthesis of Bis(indolyl)methanes

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Recyclable copper catalyst supported over ceria for acceptorless dehydrogenative synthesis of quinolines