Fachzeitschriften

Chemistry – An Asian Journal

Artikel

Synthesis of Diaryl Tellurides with Sodium Aryltellurites under Mild Conditions

von Shan Li et al.

· 12.04.2024

A highly efficient new protocol has been developed for the formation of C−Te bonds, leading to both symmetrical and unsymmetrical diaryl tellurides. This protocol utilizes sodium aryltellurites, which can be easily prepared from low-cost aryltelluri...

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Synthesis of Regioregular and Random Boron‐Fused Azomethine Conjugated Polymers for Film Morphology Control

von Shunsuke Ohtani et al.

· 12.04.2024

Regioregular and random conjugated polymers based on a boron-fused azomethine unit were synthesized. Optical measurements and microscopic observation indicated the existence of aggregation domains in the spin-coated film of the regioregular polymer ...

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NIR‐Mediated Cu2O/Au Nanomotors for Synergistically Treating Hepatoma Carcinoma Cells

von Ting Xian et al.

· 12.04.2024

A NIR-driven Janus Cu₂O/Au nanomotor had been constructed to explore the synergistical therapeutic effect on hepatoma carcinoma cells. The asymmetric Au modification causes uneven heating on both sides of the Cu₂O/Au nanomotor, resulting in autonomo...

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Phosphorescence Properties of Boron/Bismuth Hybrid Conjugated Materials

von Yohei Adachi et al.

· 12.04.2024

We synthesized thiophene–based hybrid π-conjugated materials by combining bismuth and boron and demonstrated their phosphorescence properties at room temperature. The phosphorescence properties of these compounds are strongly influenced not only by ...

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Multiple Force‐Triggered Downconverted and Upconverted Emission in Polymers Containing Diels‐Alder Adducts

von Guohua Zhu et al.

· 12.04.2024

Downconverted and upconverted emission are mechanochemically activated by ultrasound, compression and freezing, respectively, in polymers incorporated with a Diels-Alder adduct mechanophore that releases 9-styrylantharene chromophores when force is ...

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Anodization as a scalable nanofabrication method to engineer mechanobactericidal nanostructures on complex geometries

von Anindo Roy et al.

· 12.04.2024

Disconnected nanotubular topography generated using electrochemical anodization in organic electrolytes demonstrates excellent mechanobactericidal effect, similar to nanopillars found on insect wings. The structures are mechanically robust and durab...

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Schiff‐base Polymer Immobilized Ruthenium for Efficient Catalytic Cross‐coupling of Secondary Alcohols with 2‐amino‐ and γ‐aminobenzyl Alcohols to Give Quinolines and Pyridines

von Lei Li et al.

· 12.04.2024

SNW-1, a Schiff–base porous polymer, has been impregnated with ruthenium trichloride for acceptor–free dehydrogenation coupling (ADC) of secondary alcohols with γ-amino- and 2-aminobenzyl alcohols to give pyridines and quinolines. This heterogenous ...

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Water‐Doped Brønsted Acidic Protic Ionic Liquids for Enhanced Tributyl Citrate Synthesis in a Two‐Phase Esterification System

von Justyna Więcławik et al.

· 12.04.2024

A method for the synthesis of tributyl citrate plasticizer using inexpensive Brønsted acidic protic ionic liquids in a two-phase reaction system is presented. The esterification process is carried out with high yield (>99 %), selectivity (up to 9...

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A Computational Perspective on the Reactivity of π‐spacers in Self‐Immolative Elimination Reactions

von Daniele Padula

· 12.04.2024

Computational characterisation of transition states for several π-spacers adopted in self-immolative elimination reactions allows rationalising electronic effects on reaction rates, paving the way towards the in silico design of new spacers. Abstr...

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Carbon‐Sulfur Bond Cleavage in Methanesulfonate on Diorganotin Quinaldate Platform – Synthesis and Characterization of [(n‐Bu2SnL)2SO4]

von Priyanka Chauhan et al.

· 12.04.2024

Several new mixed ligand diorganotin complexes, [(n-Bu₂SnL¹⁻³)₂SO₄] and [(Me₂Sn)₂(L²)₃(OSO₂Me)] (HL= quinadic acids) have been synthesized and structurally characterized by X-ray crystallography. Abstract The synthesis of mixed ligand di-n-butylti...

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Template Assisted One‐Pot Synthesis of [2], Linear [3], and Radial [4]Catenane via Click Reaction

von Mana Bhanjan et al.

· 12.04.2024

Using a non-labile Co (III) metal template and click reaction followed by de-metalation, synthesis of [2], linear [3], and radial [4] catenane has been achieved. Synthesized templated linear [2] catenane has an additional metal binding site for the ...

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Unlocking High‐Current Performance in Silicon Anode: Synergistic Phosphorus Doping and Nitrogen‐Doped Carbon Encapsulation to Enhance Lithium Diffusivity

von Arief Muhammad et al.

· 12.04.2024

Synergistic effect of P-dopant and N-doped carbon encapsulation on ball-milled silicon nanoparticles improved Li⁺ diffusivity in silicon anode by tenfold. While N-doped carbon encapsulation mainly improves Li⁺ diffusivity, P-dopant increases the int...

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Front Cover: (Chem. Asian J. 7/2024)

12.04.2024

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Structural Insights on the Role of Halogen Bonding in Protein MEK Kinase‐Inhibitor Complexes

von Pietro Milesi et al.

· 12.04.2024

Crystal structures of protein kinase complexes with FDA-approved MEK inhibitors showcase the key role of halogen bonds in conferring specificity and affinity for binding halogenated molecules by this important class of biomacromolecules. Abstract ...

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Stimuli‐triggered Self‐Assembly of Gold Nanoparticles: Recent Advances in Fabrication and Biomedical Applications

von Yan Zhao et al.

· 12.04.2024

This review summarizes recent progress in the development of stimuli-triggered self-assembly on gold nanoparticles and introduce the breakthrough of gold nanoparticles in disease diagnosis and treatment. In addition, the current challenge and future...

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Current Development of Lanthanide Complexes for Biomedical Applications

von Mengfei Wang et al.

· 12.04.2024

Ln(III) complexes display sensitized Ln(III) emissions by energy transfer from excited ligands. The long-lived Ln(III) emissions, rangings from visible to NIR region, hold great application potential in biomedical fields. This mini–review highlights...

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Homogeneous and Heterogeneous Frustrated Lewis Pairs for the Activation and Transformation of CO2

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Na/N Co‐doped Seaweed Biochar Composite for Efficient Removal of Aqueous Pb(II) and Cu(II)

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Biomaterials for Targeting Endoplasmic Reticulum in Cancer

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Tuning Green Explosives through SNAr Chemistry

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Direct C−H Sulfuration: Synthesis of Disulfides, Dithiocarbamates, Xanthates, Thiocarbamates and Thiocarbonates

von Qiao Sun et al.

· 11.04.2024

Organic disulfides, dithiocarbamates, xanthates, thiocarbamates and thiocarbonates have attracted considerable attention from the synthetic community due to their important biological activities and widespread applications. This review systematicall...

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Light Responsive DNA Nanomaterials and Their Biomedical Applications

von Raja Muhammad et al.

· 11.04.2024

Light responsive DNA nanomaterials based on photocleavage/photodecage, photoisomerization, and photocrosslinking have been summarized for efficient bioimaging (including imaging of small molecule, microRNA, and protein) and drug delivery (including ...

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Sustainable Vat Photopolymerization‐Based 3D‐Printing through Dynamic Covalent Network Photopolymers

von Sirawit Pruksawan et al.

· 11.04.2024

This review paper focuses on sustainable materials for vat photopolymerization (VPP) based 3D printing. Recent developments in VPP 3D printable polymers with dynamic covalent bonds are summarized, showcasing their chemical recyclability, thermo-mech...

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Dual Functional Microcapsule based on Monodisperse Short PEG Amphiphile for Drug Encapsulation and Protein Affinity Controlled Release

von Rohit N. et al.

· 11.04.2024

We conjugated tetraethylene glycol, a short, neutral amphiphilic, monodisperse polymer with a benzothiazole fluorophore (TEG-BTA-2) to form a switchable self-assembled structure in an aqueous medium for functional applications. TEG-BTA-2 formed a mi...

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Organocatalyzed Hydroacylation of Enones by Photosensitization of Acyl Silanes

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Pincer Nickel‐Catalyzed Olefination of Alcohols with Benzylphosphine Oxides

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Ambient Temperature Metal‐Free Thiomethylation of Chloroheteroarenes and Chloropurines

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Electro‐oxidative Methylation of 2‐Isocyanobiaryls Using N,N‐dimethylformamide (DMF) as Carbon Source: Synthesis of 6‐Methylphenanthridines

von Kannika La‐ongthong et al.

· 10.04.2024

This study reported the synthesis of 6-methylphenanthridines from 2-isocyanobiaryls using dimethylformamide (DMF) as a methyl carbon souce. The reactions were conducted in open-air atmosphere using electrochemical process at ambient temperature. A...

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Sustainable harnessing of waste polycarbonate for synthesizing activated furans to generate Stenhouse adducts on polymer surface

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Phosphine‐Mediated Dimerization of Open‐[60]Fullerenes

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Progress in electrochemically empowered C‐O bond formation: Unveiling the pathway of efficient green synthesis

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Magnesium Magic: State‐of‐the‐Art Nanocrystalline Materials Paving the Way for Hydrogen Storage

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Revisiting Stereoselective Propene Polymerization Mechanisms: Insights through the Activation Strain Model

von Eugenio Romano et al.

· 05.04.2024

The stereoselectivity of propene polymerization catalyzed by transition metals has been revisited by the Activation Strain Model coupled with the Natural Energy Decomposition Analysis. Different homogeneous ligand frameworks have been analyzed with ...

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Synthesis of Naphthalimide Azocarboxylates Showing Turn‐On Fluorescence by Substitution Reaction with Sulfinates

von Hiroki Tanimoto et al.

· 05.04.2024

The addition reaction of sulfinates to naphthalimide-substituted azocarboxylate afforded the sulfonyl hydrazides with high quantum yields (up to 0.91 in THF and 0.54 in methanol), which exhibited a large Stokes shift (105 nm), while the unsubstitute...

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Recent Advances of Aminopeptidases‐Responsive Small‐Molecular Probes for Bioimaging

von Chengyan Xu et al.

· 05.04.2024

Aminopeptidases, a class of enzymes with critical roles in biology, are emerging as vital biomarkers for metabolic processes and diseases. Aberrant aminopeptidase levels are often associated with diseases, particularly cancer. This comprehensive rev...

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Wet‐Chemical Synthesis of Elemental 2D Materials

von Yue Xu et al.

· 05.04.2024

This review presents an extensive overview of wet-chemical synthesis techniques for elemental 2D materials (Xenes), underscoring their intrinsic properties, notable applications. It explores the cost-efficiency, high-yield benefits of wet-chemical m...

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Two Energetic Framework Materials Based on DNM–TNBI as Host Molecule: Effectively Coordinated by Different Cations

von Boqian Yang et al.

· 05.04.2024

We successfully started from DNM–TNBI and synthesized two different energetic framework materials by assembled with two different cations, [DNM–TNBI² ⁻][2NH₄ ⁺] and [DNM–TNBI² ⁻][2K⁺ ]. Both of them show better thermal stabilities than DNM–T...

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Advanced Functionalized Nanoclusters (Cu, Ag, and Au) as Effective Catalyst for Organic Transformation Reactions

von Parveen Kumar et al.

· 05.04.2024

The review emphasize the significance of advanced functionalized nanoclusters (NCs) in catalysis through an in-depth examination of current advancements in copper (Cu), silver (Ag), and gold (Au) NCs. It comprehensively examines many aspects includi...

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Recent advances in photosensitizer materials for light‐mediated tumor therapy

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Recent Advances on Diarylethene‐Based Photoswitching Materials: Applications in Bioimaging, Controlled Singlet Oxygen Generation for Photodynamic Therapy and Catalysis

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Metal‐Free Visible‐Light Catalytic Deoxygenation of Azaaryl N‐Oxides: Harnessing Photons for Efficient Greener Synthesis

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Palladium‐Catalyzed C3‐Carbaldehyde Directed Regioselective C2‐Thioarylation of Indoles

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Fluoro and Trifluoromethyl Benzoyl Hypoiodite Complexes with Substituted Pyridines

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An Air‐Stable Storage Compound for White Phosphorus: Reversible Addition to a Stannylene and Chemical Release of P4

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One‐Pot Assembly of 2‐Trifluoromethyl Benzothiazole and Benzoselenazole via Copper‐Mediated Three‐Component Cascade Reaction

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Efficient absorption of CO2 by protic‐ionic‐liquid based deep eutectic solvents

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Luminogenic and Bactericidal Studies of an Acrylonitrile‐based AIEgen

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A Porphyrin‐Based 3D Metal−Organic Framework Featuring [Cu8Cl6]10+ Cluster Secondary Building Units: Synthesis, Structure Elucidation, Anion Exchange, and Peroxidase‐like Activity

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HA‐Based pH‐Responsive Calcium Ions and Crocetin Releasing Hydrogel for Accelerating Skin Wound Healing

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Microflow, Sequential Coupling and Cyclization Approach for Synthesis of Cyclic Phosphotriesters from PCl3

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Robust Graphene‐based Aerogel for Integrated 3D Asymmetric Supercapacitors with High Energy Density

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Copper Oxide Anchored Carbon Nanofibers: A Versatile Platform for Multiplex Detection of Antibiotics, Heavy Metals and Pesticides

von Smriti Mishra et al.

· 29.03.2024

Introducing a Paradigm–Shifting Sensor Array: Enabling the Simultaneous Detection of Antibiotics, Heavy Metals, and Pesticides through the Synergy of Copper Oxide–Anchored Carbon Nanofibers Abstract Electrochemical sensors offer promising prospect...

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Development of Anisotropic Electrically Conductive GNP‐reinforced PCL‐Collagen Scaffold for Enhanced Neurogenic Differentiation under Electrical Stimulation

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Hard Carbon Derived From Different Precursors for Sodium Storage

von Wanli Wang et al.

· 28.03.2024

The upcoming grid-scale energy storage desperately requires sodium-ion batteries, whose performance is largely determined by anode materials, namely hard carbon (HC). However, the microstructures and electrochemical properties of HCs are strongly pr...

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Ce‐Doped TiO2 Fabricated Glassy Carbon Electrode for Efficient Hydrogen Evolution Reaction in Acidic Medium

von Md. Nurnobi et al.

· 28.03.2024

Ce-doped TiO₂ catalyst is synthesized through the sol-gel method, displaying significant promise as a superior electrocatalyst for the hydrogen evolution reaction (HER) in an acidic medium. The GCE-5wt.%CeTiO₂ electrode demonstrates an onset potenti...

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Recent Advances in Detection of Hydroxyl Radical by Responsive Fluorescence Nanoprobes

von Mazen Alanazi et al.

· 28.03.2024

Hydroxyl radical (•OH), one of the most aggressive reactive oxygen species, plays essential roles in the development of various diseases. The review article summarizes the advancements in characterizing •OH in living organisms using responsive nanop...

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Hollow Nitrogen‐Doped Carbon Spheres as Zincophilic Sites for Zn Flow Battery

von Han Shi et al.

· 28.03.2024

We prepare hollow N-doped carbon spheres (HNCSs) with a high specific surface and sufficient internal space. The rich space within the hollow carbon spheres relieves structural stress during long-term battery cycling. The N functional groups enhance...

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Carbazole Based Smaragdyrins: Synthesis, Aromaticity Switching, and Formation of a Spiro‐Dimer

von Jinchao Chen et al.

· 28.03.2024

Double S_NAr reaction of 3,5-dibromo-8-mesityl-BODIPY 1 with 3,6-di(tert-butyl)-1,8-di(pyrrol-2-yl)carbazole 2 gave carbazole-incorporated smaragdyrin BF₂-complex 3, which was converted to free base 4, Rh^I complex 7, and spiro dimer 8, through differ...

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Biocompatible Gold Nanoparticles‐Modified Fluorine Doped Tin Oxide Electrode for the Fabrication of Enzyme‐Free Glucose Sensor

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MXene/silk fibroin strengthened PVA‐based eutectogel with excellent self‐healing ability and environmental adaptability: Design, synthesis, and sensing application

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Facile Preparation of Impalement Resistant, Mechanically Robust and Weather Resistant Photothermal Superhydrophobic Coatings for Anti‐/De‐icing

von Jinfei Wei et al.

· 27.03.2024

The Si-PET/F-silica/CB coating was prepared by spraying a dispersion consisting of F-silica, Si-PET adhesive and photothermal CB nanoparticles onto Al alloy plates and thermal curing. The coating shows excellent superhydrophobicity, impalement resis...

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Strategic Insertion of Heavy Atom to Tailor TADF OLED Material for the Development of Type I Photosensitizing Catalytic Red Emissive Assemblies

von Manpreet Singh et al.

· 27.03.2024

The present work describes the development of the type I photosensitizer by strategic heavy atom (sulfur) insertion in TADF active OLED material for generating red emissive assemblies and their further use in photocatalytic synthesis of benzimidazol...

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Frustrated Lewis Pair‐Type Reactivity of Intermolecular Rare‐Earth Aryloxide and N‐Heterocyclic Carbene/Olefin Combinations

von Yiwen Guan et al.

· 27.03.2024

Frustrate Lewis pair-type reactivity of rare-earth (RE) metal abnormal NHC complexes and RE/NHO Lewis pairs was investigated, including synergistic H₂ activation and catalytic hydrogenation of the exocyclic C=C double bond of NHO. These combinations...

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Unraveling Ferroptosis Mechanisms: Tracking Cellular Viscosity with Small Molecular Fluorescent Probes

von Niharika Pareek et al.

· 27.03.2024

During #ferroptosis, the cells undergo disruption in cellular microenvironment such as #viscosity. In this review we focused on small molecular fluorescent probes that measures the dynamics of viscosity during ferroptosis. Abstract Ferroptosis is ...

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Controllable Chemoselectivity Cascade Reactions for the Synthesis of Phenanthrenols via Palladium‐Catalyzed‐Suzuki/Heck Reaction and Michael Addition

von Phornphan Yongpanich et al.

· 27.03.2024

Palladium, a versatile catalyst, is controllable via reaction conditions tuning. This research highlights the palladium catalyst‘s application in synthesizing phenanthrenols through a sequential cascade of Suzuki/Heck reactions between chalcone and ...

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0‐D and 1‐D Perovskite‐like Hybrid Bismuth(III) Iodides

von Aditi Saraswat et al.

· 27.03.2024

Three hybrid Bi(III) iodides are synthesized as single crystals containing face-sharing [Bi₂I₁₀]⁴⁻ dimer and cis corner-shared 1-D [BiI₅]²⁻ chain as the inorganic sublattice. This work shows that both chemical composition and structural dimensionali...

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Ultrasonic‐Assisted Nitrate Anion Incorporation in Triaminoguanidium Chloride Based Covalent Organic Polymer For Methylene Blue Dye Adsorption

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CO2‐Free Ethylene Oxide Production via Liquid‐Phase Epoxidation with Fe2O3/MSM Catalyst

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Aggregation‐Induced Emission of Naphthalene Diimides: Effect of Chain Length on Liquid and Solid‐Phase Emissive Properties

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Quinone methide based self‐immobilizing molecular fluorescent probes for in situ imaging of enzymes

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Ligand‐free MnBr2‐Catalyzed Chemo‐ and Stereoselective Hydroboration of Terminal Alkynes

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Primary Antioxidant Power and Mpro SARS‐CoV‐2 Non‐Covalent Inhibition Capabilities of Miquelianin

von Maciej Spiegel et al.

· 20.03.2024

The primary antioxidant activity and the non-covalent inhibition capacity of M^pro from SARS-CoV-2 of miquelianin, a derivative of quercetin, were investigated in the mean of DFT calculations and MD simulations respectively. From computations, dual a...

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The (o‐p‐o)‐Terphenyl Embedded Calix[2]phyrin(2.2. 1 .1. 1 ) and Its Cu(II) Complex

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Benzannulated Double Aza[9]helicenes: Synthesis, Structures, and (Chir)optical Properties

von Yusuke Matsuo et al.

· 19.03.2024

A benzannulated double aza[9]helicene was successfully synthesized via a one-pot oxidative fusion reaction, which was further derivatized to its N-alkylated ones. The X-ray structures showed double helical structures with overlapping terminal benzen...

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Advancements in Olive‐derived Carbon: Preparation Methods and Sustainable Applications

von A. H. et al.

· 19.03.2024

This review explores the potential of olive-derived carbon (ODC) for sustainable material science applications, including innovative preparation methods like pyrolysis and activation, showcasing the versatility of ODC in energy storage and environme...

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An Isolable THF‐Coordinated Dialkylgermanone

von Kazuma Oshima et al.

· 19.03.2024

A dialkylgermanone (R₂Ge=O) was synthesized and isolated as a THF-coordinated form. The reaction of the THF-coordinated dialkylgermanone with triphenylphosphine affording the corresponding germylene and triphenylphosphine oxide indicated that the Ge...

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Metal‐Organic Frameworks‐Derived Nanocarbon Materials and Nanometal Oxides for Photocatalytic Applications

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Nucleophilic Selenocyclization Reaction of Benzodiynes Promoted by Sodium Selenide: Synthesis of Isoselenochromenes

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Synthesis of R‐GABA Derivatives via Pd(II) Catalyzed Enantioselective C(sp3)‐H Arylation and Virtual Validation with GABAB1 Receptor for Potential leads

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Pd‐Catalyzed Oxidative C−H Arylation of (Poly)fluoroarenes with Aryl Pinacol Boronates and Experimental and Theoretical Studies of its Reaction Mechanism

von Yudha P. et al.

· 14.03.2024

A simple catalytic process for the C−H arylation of (poly)flluoroarenes with aryl pinacol boronates mediated by a Pd/Ag system without added ligand is reported. This reaction can be carried out in air, generating unsymmetric biaryl products in up to...

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Recent Advancements on Sustainable Electrochemical Water Splitting Hydrogen Energy Applications Based on Nanoscale Transition Metal Oxide (TMO) Substrates

von Mohsin Saeed et al.

· 14.03.2024

Nanoscale transition metal oxides (TMO) is a promising contender for generating clean and sustainable hydrogen production from water with exceptional efficiency using water splitting approach. This review article specifically examines the use of TMO...

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Boosting the Electrocatalytic Water Splitting Performance Using Hydrophilic Metal‐Organic Framework

von Munzir Suliman et al.

· 13.03.2024

The article explores the efficacy of a Pd/C@MOF-303-based electrode in improving hydrogen evolution reaction performance within an electrochemical cell. It explores the mechanism underlying this improvement. Abstract In this study, we employed a r...

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Zinc Doping Induces Enhanced Thermoelectric Performance of Solvothermal SnTe

von Lijun Wang et al.

· 11.03.2024

We report a microwave-assisted wet chemical method for doping Zn into SnTe thermoelectric materials to in-situ induce rich ZnTe nanoprecipitates, nanopores, a large number of grain boundaries and other multi-dimensional defects. While ensuring compe...

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Reactions of Heteroallenes with Salan‐based Ti(IV) Complexes: A Joint Experimental and Computational Study

von Joana Hipólito et al.

· 11.03.2024

Salan-based Ti(IV) complexes react with ^tBuNCO leading to the insertion of one or two isocyanate molecules into Ti-N_salan bonds. Conversely, the reaction of [(L*)Ti(NHMe₂)₂] (L*=N₂O₂ ⁴⁻) with CO₂ reveals its insertion into Ti-NHMe₂ bonds. The i...

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Solid‐State Emissive Pillar[6]arene Derivative Having Alternate Methylene and Nitrogen Bridges

von Shunsuke Ohtani et al.

· 11.03.2024

Herein, we synthesized pillar[6]arene derivatives having alternate methylene and nitrogen bridges. Owing to the charge transfer emission, the solid-state photoluminescence quantum yield (Φ_PL) was enhanced compared with that of the parent pillar[6]ar...

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Visible Light‐Induced Metal‐free Arylation of Coumarin‐3‐carboxylates with Arylboronic Acids

von Swarnayu Banik et al.

· 11.03.2024

A metal free photoredox strategy for alkenyl C−H arylation has been developed for the first time to synthesize a diverse range of 4-aryl coumarin-2-oxo-3-carboxylate derivatives. Abstract The present work represents a novel methodology for the sel...

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On the Existence of Pnictogen Bonding Interactions in As(III) S‐Adenosylmethionine Methyltransferase Enzymes

von Rosa M. et al.

· 11.03.2024

This study advances our understanding of As(III) interactions in biological systems, revealing the important role of pnictogen bonding in As(III) S-adenosylmethionine methyltransferases. The noncovalent As⋅⋅⋅O pnictogen bonds have been analyzed ener...

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Sodium‐Mediated Reductive C−C Bond Cleavage Assisted by Boryl Groups

von Mizuki Fukazawa et al.

· 08.03.2024

Boryl-group-assisted reductive C−C bond cleavage of 1,2-diaryl-1,2-diborylethanes is described. The substrates, 1,2-diaryl-1,2-diborylethanes, are synthesized by reductive diboration of stilbenes. The combination of these reactions, reductive dibora...

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Recent Advances in NHC‐Catalyzed Chemoselective Activation of Carbonyl Compounds

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Direct Through‐Space Substituent‐π Interactions in Noncovalent Arene–Fullerene Assemblies

von Yoshifumi Hashikawa et al.

· 07.03.2024

The substituents effects in arene-fullerene interactions were examined by NMR titration experiments using an open-[60]fullerene as a host, revealing self-assembling behavior with substituted benzenes by a 1 : 2 stoichiometry. The destabilization of ...

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Recent Advances of Chiral Small Organic Molecules: Structure and Properties for Circularly Polarized Luminescence

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Synthesis and Oxygen Evolution Reaction Application of a Co−Cd Based Bimetallic Metal‐Organic Framework

von Syed Shaheen et al.

· 06.03.2024

This research focuses on synthesizing a novel bimetallic metal-organic framework with a distinctive structure with distorted octahedral chains of CoO and CdO, linked by benzene tricarboxylic acid (BTC). Electrochemical testing revealed that bimetall...

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Alkoxylated Fluoranthene‐Fused [3.3.3]Propellanes: Facile Film Formation against High π‐Core Content

von Kenichi Kato et al.

· 06.03.2024

Structural, thermal, and optical properties reveal that amorphous assembling is easily attained in a series of fluoranthene-fused [3.3.3]propellanes with a rigid 3D skeleton bearing n-butoxy or longer alkoxy groups. Drop-cast films can be obtained d...

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Tuning Sensing Efficacy: The Influence of Alkyl Substituents on Metal Ion Detection at Mesoscopic Interface

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Non‐Linear Optical Activity of Chiral Bipyrimidine‐Based Thin Films

von Prescillia Nicolas et al.

· 29.02.2024

Solid-state supramolecular organization of bipyrimidine cores functionalized with alkoxystyryl moieties bearing short chiral chains allows for the emergence of strong high order harmonic signals from thin films obtained without any corona-poling pro...

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Hydrogenation of CO2 into Value‐added Chemicals Using Solid‐Supported Catalysts

von Mahbuba Aktary et al.

· 28.02.2024

This review discusses the prospect of utilizing earth-abundant CO₂ as a feedstock for value-added chemicals via hydrogenation reaction. The recent progress of CO₂ mitigation strategies using solid-supported catalysts and its opportunities for conver...

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The dopamine D2 receptors antagonist Veralipride inhibits carbonic anhydrases: solution and crystallographic insights on human isoforms

von Andrea Angeli et al.

· 26.02.2024

This study explores veralipride, a benzamide-class antipsychotic and dopamine D2 receptor antagonist, for its inhibitory effects on carbonic anhydrase (CA) isoforms. In vitro profiling reveals potent inhibition across hCA I, II, and CA XII. In addit...

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Ferrocene‐Boosted Nickel Sulfide Nanoarchitecture for Enhanced Alkaline Water Splitting

von Abeera Hassan et al.

· 15.02.2024

This study employs a one–step solvothermal approach to incorporate ferrocene (Fc) into nickel sulfide nanostructures, revealing exceptional electrocatalytic performance with an overpotential of 290 mV@10 mA cm⁻², surpassing traditional nickel sulfid...

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Engineering Mn‐Doped CdS Thin Films Through Chemical Bath Deposition for High‐Performance Photoelectrochemical Water Splitting

von Nimrah Tahir et al.

· 09.02.2024

Single phase Mn-doped CdS thin films were successfully synthesized by the chemical bath deposition. Different morphologies like nano-cubes, nanoflakes, nano-worms, and nanosheets were obtained under different deposition conditions. The optimized Mn-...

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In Situ Spectroscopic Study of CO2 Capture and Methanation over Ni−Ca Based Dual Functional Materials

von Shinta Miyazaki et al.

· 06.02.2024

In this study, we investigate the mechanism of CCR to CH₄ over Al₂O₃-supported Ni−Ca DFMs. Various spectroscopic analyses, including time-resolved in situ XRD and XAS, were conducted during CO₂ capture and the subsequent H₂-reduction steps. Abstra...

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Interparticle Hydrogen Spillover in Enhanced Catalytic Reactions

von Ken Motokura

· 06.02.2024

We analyze examples of enhanced catalysis based on interparticle (reverse) hydrogen spillover. Simple physical mixtures of powdered catalysts containing metal catalysts of H₂ dissociation/recombination and solid catalysts with active sites for subst...

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Syngas Production by Chemical Looping Dry Reforming of Methane over Ni‐modified MoO3/ZrO2

von Zen Maeno et al.

· 22.01.2024

Ni-modified molybdenum zirconia (Ni/MoO₃/ZrO₂) was developed as an effective oxygen storage material for chemical looping dry reforming of methane (CL–DRM) under isothermal reaction conditions of 650 °C, which was 100–200 °C lower than the previousl...

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Poly[(2‐methacryloyloxy)Ethyl]Trimethylammonium Chloride Supported Cobalt Oxide Nanoparticles as an Active Electrocatalyst for Efficient Oxygen Evolution Reaction

von Santa Islam et al.

· 28.12.2023

Water splitting is viewed as a clean substitute for fossil fuels and as the most promising approach for quickly producing hydrogen fuel. The oxygen evolution process (OER), which yields oxygen as the sole byproduct at the anode of a water electrolyz...

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At the limits of bisphosphonio‐substituted stannylenes

von Sina Nasemann et al.

· 27.12.2023

Bisphosphoniostannylenes and plumbylenes have been embedded into [3]ferrocenophane scaffolds staying monomeric for the stannylenes and dimerice via halide bridges for the plumbylene. The compounds are dynamic in solution which can be suspended with ...

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Water Solubilization and Guest Molecule‐Induced Fluorescence Changes of Porous Host Molecules via Complexing with Polysaccharide or Polypeptide

von Sota Umezane et al.

· 21.12.2023

N,N’-bis(2-aminobenzophenone)-1,4,5,8-naphthalenetetracarboxylic diimide (1) can dissolve in aqueous solutions via complexation with λ-carrageenan and the complex could include small aromatic guest molecules such as benzene, toluene, and xylene with...

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Enhanced Electrocatalytic Activity of Amorphized LaCoO3 for Oxygen Evolution Reaction

von Amna Altaf et al.

· 28.11.2023

Increasing energy demands and fossil fuel depletion urges scientists to develop renewable catalysts for energy production. Amorphous catalysts are the emerging electrocatalysts due to their structural flexibility. Herein, crystalline LaCoO₃ is trans...

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CZTS (Cu2ZnSnS4)‐based Nanomaterials in Photocatalytic and Hydrogen Production Applications: A Recent Progress towards Sustainable Environment

von Himadri Tanaya et al.

· 08.11.2023

The illustrative description for the synthesis method of CZTS and their distinctive morphological effects are explained in this review. The potential scope of CZTS utilization in wastewater-cleaning through photocatalytic dye-degradation is thorough...

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Recent Advancements in Metal‐Organic Framework‐Based Membranes for Hydrogen Separation: A Review

von Umair Baig et al.

· 02.11.2023

Recent advancements in the development of metal-organic framework-based membranes using various fabrication strategies for hydrogen gas separation are covered in this review. Abstract Metal-organic frameworks (MOFs) are promising porous materials ...

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Utilizing Nanostructured Materials for Hydrogen Generation, Storage, and Diverse Applications

von Mohsin Saeed et al.

· 30.10.2023

Recent progress in the nanoscale synthesis of metal-containing nanoscale materials, ultra-high surface area nanoporous materials and other functionalities has exbited a notable significant impact on the field of hydrogen storage, particularly in the...

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Transition‐metal‐based Catalysts for Electrochemical Synthesis of Ammonia by Nitrogen Reduction Reaction: Advancing the Green Ammonia Economy

von Riva Akter et al.

· 25.10.2023

Leveraging the electrochemical nitrogen reduction reaction (NRR) presents a paradigm shift towards environmentally benign ammonia production operating under ambient conditions. This review encapsulates the forefront of research on Ru- and Mo-based e...

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Recent Advances in Bimetallic Catalysts for Methane Steam Reforming in Hydrogen Production: Current Trends, Challenges, and Future Prospects

von Basiru O. et al.

· 25.10.2023

The primary method for hydrogen production is through methane steam reforming (MSR) of natural gas. This process involves the reaction between methane and steam to create a synthesis gas (syn gas). Following this, a step referred to as water-gas shi...

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Advancements in Biomass‐Derived Activated Carbon for Sustainable Hydrogen Storage: A Comprehensive Review

von Ar Rafi et al.

· 25.10.2023

This review explores the potential of biomass-derived activated carbon (AC) as a pivotal solution for hydrogen storage challenges. Highlighting its eco-friendliness, cost-effectiveness, and superior adsorption qualities, the work navigates through t...

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High‐Selectivity Hydrogen Gas Sensors based on Mesoporous PbOx‐ZnO Nanocomposites

von Umesh Fegade et al.

· 04.10.2023

Hydrogen is a promising renewable and environmentally friendly energy carrier, carries inherent risks owing to its highly flammable nature. A mere 4 % concentration of hydrogen in the air can trigger an explosion. To counteract this peril, a composi...

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Chemiresistive Gas Sensing using Graphene‐Metal Oxide Hybrids

von Mohammad Kamal et al.

· 20.09.2023

This review focuses on graphene-functionalized metal oxide nanostructures designed for gaseous molecules detection, mainly hydrogen gas sensing applications. Perfect structured pristine graphene (left-top), electron-hole transport mechanism in metal...

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Harnessing Nanomaterials for Enhanced Biohydrogen Generation from Wastewater

von I. Ihsanullah et al.

· 08.09.2023

The present review describes an overview of the role of nanomaterials in biohydrogen production from wastewater. Abstract Biohydrogen is considered a green fuel due to its eco-friendly nature since it only produces water and energy on combustion. ...