Carbon capture, utilization, and storage (CCUS) are among the key technologies to achieve large-scale carbon emission reduction globally. Deep eutectic solvents (DESs) are considered as designable solvents, which has attracted intensive attention ...
Artikel
One‐Pot Assembly of 2‐Trifluoromethyl Benzothiazole and Benzoselenazole via Copper‐Mediated Three‐Component Cascade Reaction
Chemistry – An Asian Journal, April 2024, DOI. Login für Volltextzugriff.
Von Wiley-VCH zur Verfügung gestellt
A domino one-pot synthesis of 2-(trifluoromethyl)benzothiazole via copper-mediated three-component cascade reaction starting from the easily accessible starting materials such as o-iodoanilines, methyl trifluoropyruvate, and elemental sulfur is reported. The present strategy displayed a comprehensive substrate scope and good functional group tolerance and enabled access to a variety of substituted 2-(trifluoromethyl)benzothiazoles. A 2-(trifluoromethyl)benzoselenazole has also been synthesized utilizing this reaction methodology.
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