The substituents effects in arene-fullerene interactions were examined by NMR titration experiments using an open-[60]fullerene as a host, revealing self-assembling behavior with substituted benzenes by a 1 : 2 stoichiometry. The destabilization ...
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Recent Advances in NHC‐Catalyzed Chemoselective Activation of Carbonyl Compounds
Chemistry – An Asian Journal, April 2024, DOI. Login für Volltextzugriff.
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N-Heterocyclic carbenes (NHCs) catalysts have been employed as effective tools in the development of various reactions, which have made notable contributions in developing diverse reaction modes and generating significant functionalized molecules. This review provides an overview of the recent advancements in the chemo- and regioselective activation of different aldehydes using NHCs, categorized into five parts based on the different activation modes. A brief conclusion and outlook is provided to stimulate the development of novel activation modes for accessing functional molecules.
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