ArtikelMicrowave‐Assisted Reductive Amination of Aldehydes and Ketones Over Rhodium‐Based Heterogeneous Catalystsvon Fabio Bucciol et al. · 27.03.2023 Different natural-occurring aldehydes and ketones have been selected as substrates for MW-assisted reductive amination over commercial and homemade Rh supported catalysts. MW combined with Rh catalysts allowed 98.2 % yield in benzylamine from benzal...
ArtikelEffects of Various Valence Ions on an Aqueous Rechargeable Zn//Polyaniline‐coated ZnMn2O4 Batteryvon Yu Liu et al. · 27.03.2023 The effects of various valence ions on an aqueous rechargeable Zn//Polyaniline-coated ZnMn2O4 battery are reported in this work. Combing the experimental results and the theoretical calculations, it was found that the Na+ ions can effectively suppre...
ArtikelA Second‐Order Nonlinear Optical Material Consisting of Two π‐Conjugated Groupsvon Minjuan Li et al. · 27.03.2023 The combination of two π - conjugated groups [C(NH2)3]+ and (C3N3S3)3− build a new metal-free nonlinear optical material, exhibiting a large SHG efficiency (2.0×KDP) and a moderate birefringence 0.067 at 550 nm. Abstract This work reports a new se...
ArtikelUnraveling the Nature and Strength of Non‐Covalent Interactions on the Surface of Fullerenesvon Michio Yamada · 23.03.2023 The surface properties of fullerenes are vastly dissimilar to those of conventional aromatic compounds. Specifically, the nature and strength of the intermolecular forces that act on the surfaces of fullerenes are a crucial topic for the application...
ArtikelEffects of Molybdenum Doping on the Enhanced Electrocatalytic Nitrogen Reduction Reaction Performance of CeO2 Nanorods: Theoretical and Experimental Investigationsvon Cheng Nan et al. · 23.03.2023 A series of molybdenum-doped CeO2 nanorod catalysts were successfully fabricated via a hydrothermal reaction coupled with high temperature calcination. The obtained 5 %-Mo-CeO2 nanorods provide as a superior electrocatalyst in neutral electrolytes o...
ArtikelDevelopment of Carbon Nanotube/Graphene‐Based Alginate Interpenetrating Hydrogels for Removal of Antibiotic Pollutantsvon Kaijie Ni et al. · 23.03.2023 A novel interpenetrating polymer network (IPN) hydrogel containing GO, CNT and urea-modified alginate was facilely prepared. It shows an enhanced thermal stability and can be used as an effective and reusable adsorbent for multiple antibiotics.Ni, G...
ArtikelImportance of the Nature of Acidic Sites of Different Aluminosilicates on Fixation of Carbon Dioxide with Styrene Oxidevon Aishwarya Ramesh et al. · 23.03.2023 The nature of acidic sites in commercially available aluminosilicates, zeolite Na−Y, zeolite NH4 +-ZSM-5, and as-synthesized Al-MCM-41 have been investigated by employing them as catalysts for capturing CO2 by styrene oxide. TPD studies indicate the...
ArtikelBis(triarylmethylium)‐type Macrocyclic Dications: Mechanochromic Emission Extending to the Red Regionvon Yusuke Ishigaki et al. · 23.03.2023 Since triarylmethyliums absorb visible light, their emissions can be extended to longer wavelengths than their absorptions. The constrained structure of macrocyclic dications is the key to realizing the emission extending to the red region. Thus, te...
ArtikelAntimicrobial Photodynamic Therapy for the Remote Eradication of Bacteriavon Evelias Yan et al. · 23.03.2023 Multi-drug resistant bacterial infections are indeed a great threat to the global healthcare. In this review, we would explore the significance of antimicrobial photodynamic therapy in eradicating these bacteria strains and present in summary the re...
ArtikelMolecular Design for Symmetric All‐Organic Batteriesvon Haoyu Guo et al. · 23.03.2023 The requirements of organic electrode materials (OEMs) for symmetric all-organic batteries (SAOBs) are discussed in this review article, which classifies the SAOBs based on the types of OEMs (n-type and bipolar). The recent progress on different typ...
ArtikelHow to Open the Ring of a Di‐ene‐Substituted‐δ‐Valerolactone: From Carbon Dioxide and 1,3‐Butadiene to Functional Polyestersvon Kaihao Chen et al. · 23.03.2023 EVL is a di-ene-substituted lactone derived from carbon dioxide and 1,3-butadiene. Several reactions that open its lactone ring have been reported. In polymerization field, reconstructing the monomer and introducing active comonomers are both availa...
ArtikelMono‐ and Dinuclear Gold(I) Coumarin Complexes: Luminescence Studies and Singlet Oxygen Productionvon Carlota Sobrerroca et al. · 13.03.2023 The synthesis and characterisation of a new coumarin chromophore containing a thiol group at its terminal position has been reported in this work. This chromophore has been coordinated to several gold(I) phosphane moieties to yield four different mo...
ArtikelSelf‐Induced and Progressive Photo‐Oxidation of Organophosphonic Acid Grafted Titanium Dioxidevon Nick Gys et al. · 10.03.2023 The progressive degradation of organophosphonic acid grafted TiO2 under ambient light in the presence of moisture is reported in this work. The P−C bonds are cleaved in tandem with phosphate formation and oxidation of the carbon chain, while the Ti...
ArtikelRu−Ni Alloy Nanoparticles Loaded on N‐Doped Amphiphilic Mesoporous Hollow Carbon@silica Spheres as Catalyst for the Hydrogenation of α‐Pinene to cis‐Pinanevon Shu‐Kun Liu et al. · 09.03.2023 Highly-dispersed Ru−Ni nanocatalysts were prepared by a multi-step reaction including emulsion polymerization, domain-limited carbonization, and impregnation-deposition of metals.This nanocatalyst exhibits excellent catalytic activity and selectivit...
ArtikelSynthesis of a BINOL‐Based C3 Symmetric Schiff Base and Its Fluorescence Response to Zn2+von Kai Lu et al. · 09.03.2023 A novel C 3 symmetric 1,1’-binaphthyl-based Schiff base has been synthesized. This molecule shows greatly increased sensitivity and selectivity over the other 1,1’-binaphthyl-based C 2 and C 1 symmetric probes in the fluorescent recognitio...
ArtikelPeriodic Mesoporous Ionosilica Nanoparticles for BODIPY Delivery and Photochemical Internalization of siRNAvon Braham Mezghrani et al. · 08.03.2023 Periodic mesoporous ionosilica nanoparticles incorporating porphyrin, a fully biocompatible multifunctional platform, exhibit the ability to perform photodynamic therapy, gene therapy by siRNA transport as well as the delivery of small hydrophobic m...
ArtikelAggregation‐Induced Electrochemiluminescence and Nitric Oxide Recognition by Halogen Bonding with a Ruthenium(II) Complexvon Yafang Gao et al. · 08.03.2023 A new ruthenium-based complex exhibited a good NO response based on its aggregation-induced electrochemical luminescence (AIECL) properties in the presence of a poor solvent (H2O). A detection limit of 2 nM was obtained with 5 orders of magnitude li...
ArtikelHigh‐Valence Metal‐Organic Framework Materials Constructed from Metal‐Oxo Clusters: Opportunities and Challengesvon Chen Wang et al. · 02.03.2023 Common metal-oxo clusters and their application as metal sources in the synthesis of MOFs are discussed in this Review article, with emphasis on the studies published to date on the preparation of high-valence MOF separation membranes by Group IV me...
ArtikelTreatment of Pulp Black Liquor with an Ionic Liquid: Modeling and Optimization by Using Response Surface Methodology and Central Composite Designvon Nicolas Papaiconomou et al. · 01.03.2023 Selective removal of polyphenolic polymers, polysaccharides and organic acids present in pulping factory wastewater, so-called black liquor, was studied using an ionic liquid tetrahexylphosphonium chloride. Optimised conditions were obtained using a...
ArtikelHydrophobization of a TIP60 Protein Nanocage for the Encapsulation of Hydrophobic Compoundsvon Maika Yamashita et al. · 01.03.2023 Encapsulation of hydrophobic molecules in protein-based nanocages is a promising approach for dispersing them in water. In this study, the interior surface of the artificial protein nanocage TIP60 is chemically modified with hydrophobic compounds. T...
ArtikelBis(acyl)phosphide ‐ Ambidentate Ligands for the Synthesis of Group 14 and 15 Main Group Element Compoundsvon Anna Widera et al. · 01.03.2023 The coordination behaviour of the bis(acyl)phosphide ion (BAP−) with group 14 and 15 elements was investigated. Differently than its lighter analogue, acetylacetonate (acac−), BAP− coordinates either in a chelating manner via the oxygen atoms or via...
ArtikelA Non‐Hydrolysis Reaction‐Based Imine for Fluorescence Response toward Al3+ Ions with Extremely High Selectivityvon Xu Jiang et al. · 01.03.2023 A hydrophobic 1,1’-binaphthyl-2,2’-diamine containing two amine groups was introduced to synthesize a probe bearing two imine bonds linked by two salicylaldehyde (SAs). The hydrophobicity of binaphthyl moiety and the unique clamp-like structure form...
ArtikelFiber Spinning of Ultrahigh Molecular Weight Isotactic Polypropylene: Melt Spinning and Melt Drawingvon Lucas Stieglitz et al. · 01.03.2023 Fiber spinning of ultrahigh molecular weight isotactic polypropylene was achieved by melt spinning and melt drawing. The received fibers were analyzed regarding their crystallinity and crystal phases and advantages of an ultrahigh molecular weight o...
ArtikelBimetallic Metal‐Organic Frameworks (BMOF) and BMOF‐ Incorporated Membranes for Energy and Environmental Applicationsvon K. R. et al. · 01.03.2023 Gomathi Nageswaran and co-workers (Indian Institute of Space Science and Technology) with a Review article discussing bimetallic metal-organic frameworks (BMOF) and BMOF-incorporated membranes for energy and environmental applications Abstract Bim...
ArtikelAutomated Supramolecular Polymerization in a Microflow: A Versatile Platform for Multistep Supramolecular Reactionsvon Kae Yamashita et al. · 28.02.2023 Directional supramolecular copolymerization was performed in a new type of microflow channel. Injection of monomers, selective reactions, recovery of monomers, and purification of supramolecular products are conducted in a single flow process in thr...
ArtikelSupramolecular Control of Photonic Response and Sensing of Nitricoxide using Iron(III) Corrole Monolayers and Their Stacksvon Lennart Graewe et al. · 28.02.2023 The sensitivity of amphiphilic iron(III) corrole sensing layers for the detection of nitric oxide (NO) can be controlled by lateral compression during deposition of the monolayers at the air-water interface. The spectral responses of the monolayer s...
ArtikelIron(III) Arylhydrazone Complexes Immobilized on Amine‐Functionalized Mesoporous Silica: Catalysts for the Valorization of Biomass‐Derived Furfuryl Alcoholvon Mohamed M. et al. · 28.02.2023 Highly efficient conversion of biomass-derived furfuryl alcohol into value-added products by iron(III) arylhydrazone complexes immobilized on amine-functionalized mesoporous silica is reported in this work. A highly favorable effect of microwave irr...
ArtikelKinetically Stabilized Diarylpnictogenium Ionsvon Marvin Janssen et al. · 28.02.2023 The preparation and full characterization of the stibenium and bismuthenium ions completes the series of kinetically stabilized heavier pnictogenium ions [RindMesE]+ (E=P, As Sb, Bi). The different colours of the species within this series were attr...
ArtikelFacile One‐Step Access to Pyrrole‐Based 1,4‐Diphosphabarrelenesvon Janina A. et al. · 28.02.2023 A simple approach to 1,4-diphosphabarrelenes by a one-step synthesis using commercially available starting materials is reported. In addition, the ligand properties and the coordination chemistry of the new caged phosphines are explored. Abstract ...
ArtikelEnhanced Host‐Guest Association and Fluorescence in Copolymers from Copper Salphen Complexes by Supramolecular Internalization of Anionsvon Paulina Hernández‐Pacheco et al. · 28.02.2023 One-color cached light beacons. Fluorescence performance of a new Cu−Salphen coordination compound showed blue-shifted turn-on one-order of magnitude higher luminescence when protected by copolymerization to acrylic monomers in chains of different s...
ArtikelFront Cover: Enhanced Host‐Guest Association and Fluorescence in Copolymers from Copper Salphen Complexes by Supramolecular Internalization of Anions (ChemPlusChem 3/2023)von Paulina Hernández‐Pacheco et al. · 28.02.2023 The cover picture shows a fluorescent Cu-Salphen host crystal structure interacting with an anion guest pink sphere that emits in the yellow-green region represented by fireflies, as well as the counterparts linked to a polymer chain represented as ...
ArtikelCover Feature: Automated Supramolecular Polymerization in a Microflow: A Versatile Platform for Multistep Supramolecular Reactions (ChemPlusChem 3/2023)von Kae Yamashita et al. · 28.02.2023 The cover feature image shows three-stream flows generated in microflow channels, which provide versatile reaction fields for automated supramolecular polymerization, realizing multiple operations: the injection of monomers, selective reactions, rec...
ArtikelSteric Control in Activator‐Induced Nucleophilic Quencher Detachment‐Based Probes: High‐Contrast Imaging of Aldehyde Dehydrogenase 1A1 in Cancer Stem Cellsvon Masahiro Oe et al. · 28.02.2023 The cover feature image shows a depiction of cancer stem cell detection using turn-on fluorescence probe. The quenched probe selectively responds to aldehyde dehydrogenase 1A1 (ALDH1A1) overexpressed in cancer stem cells to emit deep red fluorescenc...
ArtikelGold Triangular Nanoprisms: Anisotropic Plasmonic Materials with Unique Structures and Propertiesvon Jiangming Wang et al. · 28.02.2023 Recent research progress of gold triangular nanoprisms (AuTNPs) are discussed in this Review article. AuTNPs, a novel kind of two-dimensional nanomaterial, are discussed from three perspectives, that is, synthesis methodology, morphological evolutio...
ArtikelLuminescent Lanthanide Complexes for Effective Oxygen‐Sensing and Singlet Oxygen Generationvon Yuichi Kitagawa et al. · 29.03.2023 Oxygen quantification using luminescence has attracted attention for clinical analysis and environmental monitoring. The reaction produces singlet oxygen which is used for photodynamic cancer therapy, photo-oxidation of toxic molecules, and the phot...
ArtikelThe Alchemist, Metal‐Divider and Transmuter Carl F. Wenzel and his 1776 Award from the Royal Danish Academy of Sciences through Professor C. G. Kratzensteinvon Curt Wentrup · 28.03.2023 A metal worker's laboratory: from Georg Agricola, De re Metallica, Libri XII, Basel, 1556, illustrating a reverberatory oven similar to what Carl Wenzel would have used to divide his metals in the 1770s. This Perspective essay discusses Wenzel, who ...
ArtikelOn the Reactivity of Mes*P(PMe3) towards Aluminum(I) Compounds – Evidence for the Intermediate Formation of Phosphaalumenesvon Samuel Nees et al. · 28.03.2023 Phospha-Wittig reagent Mes*P(PMe3) reacts with different Al(I)-species to give C−H bond activated products, namely 1,2-P,Al-tetrahydronaphtalene derivatives, via an intermediate phosphaalumene. Depending on the Al(I) source the putative phosphaalume...
ArtikelÄ‐Coupling Dielectric Functionality with Magnetic Properties in Coordination Metal Complexesvon Yoshihiro Sekine et al. · 28.03.2023 The cover feature image illustrates the conceptual design of synergetic or coexistence of magnetic and dielectric functionalities in the coordination metal complexes. The coordination metal complexes can exhibit flexibility in their electronic/magne...
ArtikelDeprotonation‐Induced Color Modulation in N,N'‐Dihydroxynaphthalenediimide‐Based Organic Crystalsvon Tappei Tanabe et al. · 28.03.2023N,N’-dihydroxy-1,4,5,8-naphthalenetetracarboxdiimide (NDI-(OH)2) has attracted much attention in recent years, because its doubly deprotonated state, (O-NDI-O)2–, has metal-coordination ability and characteristic electronic transition useful for desi...
ArtikelSolvent‐Free Synthesis of S,N‐Doped Carbon Dots for Extended Visible‐Light‐Induced Oxidase‐Mimicking Activities and Antimicrobial Applicationsvon Neha Kaushal et al. · 27.03.2023Photo-oxidase nanozymes are emerging enzyme-mimicking materials that produce reactive oxygen species (ROS) upon light illumination and subsequently catalyze the oxidation of the substrate. Carbon dots are promising photo-oxidase nanozymes due to thei...
ArtikelStructural Analysis of Phase Change Materials (PCMs)/Expanded Graphite (EG) Composites and Their Thermal Behavior under Hot and Humid Conditionsvon Kai Yang et al. · 23.03.2023Expanded graphite (EG) has been used to store phase change materials (PCM) to enhance thermal conductivity and avoid leakage. However, systematic investigation on physical structure of various embedded PCMs in EG is not reported. Besides, effect of e...
ArtikelIncorporation of Bismuth Increases the Electrocatalytic Activity of Cobalt Borates for Oxygen Evolution Reactionvon Belvin Thomas et al. · 23.03.2023 Cobalt borates doped with Bi that show high electrocatalytic activity for the oxygen evolution reaction (OER) in water splitting are reported. This is the first time that Bi is demonstrated to render transition metal borates highly electrocatalytic ...
ArtikelRoxarsone Delivery Nanocomposite Based on Nitrite‐Functionalized Mesoporous Polydopamine for Multidrug‐Resistant Bacterial Infections via Enhanced Chemo‐Photothermal Therapyvon Zhecheng Kang et al. · 22.03.2023Current treatments for infections caused by multidrug-resistant bacteria still remain challenging and therapeutic materials with highly efficacy are of demand. Herein, a bactericidal nanocomposite was constructed by loading Roxarsone (ROX) onto nitro...
ArtikelPhosphine‐Catalyzed Activation of Phenylsilane for Benzaldehyde Reductionvon Rémi F. et al. · 21.03.2023 Trialkylphosphines were used as organocatalysts for the hydrosilylation of benzaldehyde to arylbenzyloxyhydrosilanes at room temperature. The products were obtained in yields up to 97 %. The nucleophilicity of the catalyst was demonstrated to be cri...
ArtikelThe Chemistry of P=N‐P=X (X = S, O, NR) Linkages for the Synthesis of Dendritic Structuresvon Valérie Maraval et al. · 21.03.2023The Staudinger reaction between a phosphine and an azide, applied to phosphorus azides, has been used for the synthesis of a large variety of dendritic structures, incorporating P=N-P=X moieties (X = mainly S, but also O and N-R). Conjugation of the ...
ArtikelOptical Properties and Metal‐Dependent Charge Transfer in Iodido Pentelatesvon Jakob Möbs et al. · 20.03.2023Lead-free heavy halogenido metalates are currently under intense investigation, as they show similar promising semiconducting properties as their famous but toxic lead relatives. A major interest in this regard is the understanding and control of opt...
ArtikelResidual Dipolar Coupling Based Conformational Analysis Allows the Configurational Assessment of Steroids with up to Eight Stereocentersvon Luca Venturi et al. · 16.03.2023 In the present work, Residual Dipolar Couplings (RDCs) were used for the conformational and configurational study of synthetic steroids with up to eight stereocenters – prednisone and beclomethasone dipropionate (BDP) –. For both molecules the corre...
ArtikelOn the Barton Copper‐Catalyzed C3‐Arylation of Indoles using Triarylbismuth bis(trifluoroacetate) Reagentsvon Ahmed Fnaiche et al. · 15.03.2023 The C3-arylation of C2-substituted indoles using Barton's protocol is investigated. The reaction is performed using triarylbismuth bis(trifluoroacetates) and is catalyzed by copper bis(trifluoroacetate). The reaction operates under mild conditions, ...
ArtikelSynthesis of Hydrogen‐Bonded Open‐[60]Fullerenol Dimersvon Yoshifumi Hashikawa et al. · 15.03.2023Two open-[60]fullerenols were synthesized through a selective bond cleavage by reactions with N-oxide or singlet oxygen. Both open-[60]fullerenols having a bis(hemiketal) moiety were aggregated via intra- and intermolecular hydrogen-bondings to show ...
ArtikelNon‐covalent interactions in the self‐assembly of dihydropyridone supermolecules and in vitro anti‐cancer assessment in human lung adenocarcinoma cell line (A549)von Brilliant et al. · 13.03.2023The synthesis of dihydropyridone derivatives has been reported by ring rearrangement of pyrans using iodine and formic acid as a catalyst separately. Dihydropyridones were crystallized subjected for single-crystal X-ray crystallography to acquire the...
ArtikelBis‐Catecholamide‐Based Materials for Uranium Extractionvon Guillaume Mossand et al. · 09.03.2023 Extraction of uranium from seawater constitutes a good alternative to mining but needs to develop solid materials with large adsorption capacity and high selectivity for uranium in presence of competitive cations. This work highlights the developmen...
ArtikelPhosphinine Selenide: Noncovalent Interactions with Organoiodines and Elemental Iodine, and Reactivity towards Potassium Cyanidevon Jinxiong Lin et al. · 09.03.2023 A phosphinine selenide has been characterized crystallographically for the first time in this work. The phosphorus heterocycle forms cocrystals with 1,4-diiodotetrafluorobenzene as well as an adduct with elemental iodine. Several types of non-bondin...
Artikel1‐Phospha‐butadienes and 1H‐phospholes via alkynylation of acetylenic phosphaalkenesvon Muhammad et al. · 06.03.2023Carbon-rich motifs are important building blocks for the fabrication of functional and opto-electronic materials. Electronic tuning can be achieved by alteration of bonding topologies but also via incorporation of heteroelements, e.g. phosphorus. Her...
ArtikelCu‐MOF‐808 as a Sensing Material for Gaseous Hydrogen Sulfidevon Nele Marquardt et al. · 06.03.2023The selective detection of hydrogen sulfide (H2S) is an important task because of its potentially hazardous effects not only on the environment but also on human health. Here, we present the zirconium-based MOF-808, which was modified with copper sal...
ArtikelFrom a Fluorenyl Substituted Ylide‐Functionalized Phosphine to a Neutral Phosphide via P−C Bond Cleavagevon Julian Löffler et al. · 03.03.2023 The attempted synthesis of a 9-methylfluorenyl-substituted ylide-functionalized phosphine is reported, which results in the formation of a secondary phosphine by elimination of methylenefluorene. This phosphine features interesting coordination prop...
ArtikelReactivity of a Cationic Bismuth Amide towards Unsymmetric Heterocumulenesvon Kai Oberdorf et al. · 09.02.2023 The smooth and highly selective insertion of ketenes (R2C=C=O) and iso(thio)cyanates (R'N=C=O, R'N=C=S) into the Bi−N bond of a cationic bismuth amide is reported. The regioselectivity of these transformations mirrors the preference of the softly Le...
ArtikelEffective Nitric Oxide Reduction over Core‐Shell Cu‐SSZ‐13@meso‐MOx Catalysts with Significant Catalytic Activity and Hydrothermal Stabilityvon Li Yun-hui et al. · 09.02.2023In this study, Cu-SSZ-13 zeolites are successfully coated with mesoporous metal oxides (CeO2, Fe2O3, TiO2 and SiO2) and prepared as core-shell Cu-SSZ-13@meso-MOx samples with hierarchical pore structure. Compared with Cu-SSZ-13, the catalytic activit...
ArtikelA Tetranuclear Copper(II)/Calcium(II) Complex as Dual Chemosensor for Colorimetric and Fluorescent Detection of Non‐Steroidal Anti‐Inflammatory Drugsvon Eleonora Macedi et al. · 31.01.2023 The cover feature image depicts a tetranuclear Cu2+/Ca2+/Ca2+/Cu2+ maltol-based platform, which has been proposed as a tool for the detection and sequestering of anionic species via a colorimetric mechanism or an indirect fluorescent sensing. The pl...
ArtikelA Tool, an App and a Field: Fluorescent PET Sensors, Blood Electrolyte Analysis and Molecular Logic as Products of Supra‐molecular Photoscience from Northern Ireland and Sri Lankavon Chao‐Yi Yao et al. · 31.01.2023 The cover feature image shows chemical species (in gold) rushing in to bind with receptors (in green) so that light signals of associated fluorophores (in blue) are switched from ‘off’ to ‘on’. Plastic chips containing such fluorescent PET sensor sp...
ArtikelTriorganylphosphoranides: Realization of an Unusual Structural Motif Utilizing Electron Withdrawing Pentafluoroethyl Groupsvon Mira Keßler et al. · 31.01.2023 Fluoride addition to P(C2F5)3 and P(C2F5)2(CN) furnished respective [P(C2F5)3F]− and [P(C2F5)2(CN)F]− salts, featuring the unusual structural motif of small, open-chained phosphoranides with three phosphorus carbon bonds. This work reports upon the ...
ArtikelLipophilic N‐Hydroxyimide Derivatives: Design, Synthesis, and Application to Aerobic Alkane Oxidation Under Neat Conditionsvon Takaya Kaneiwa et al. · 31.01.2023 The cover feature image shows aerobic C-H oxidation of hydrocarbon by lipophilic N-hydroxyimides. Novel N-hydroxyimides flanked by alkyl substituents exhibited excellent solubility in hydrocarbons, allowing high-turnover oxidation of neat cyclohexan...
ArtikelOn‐Surface‐Assembled Single‐Layer Metal‐Organic Frameworks with Extended Conjugationvon Jing Liu et al. · 31.01.2023 The cover feature image shows the construction of single-layer metal-organic frameworks with extended conjugation (SL-cMOFs) by on-surface coordination assembly. SL-cMOFs exhibit electronic bands that lead to high conductivity or non-trivial quantum...
