In the acetonitrile (AN)-ethylene carbonate (EC) electrolyte, the electrochemically stable EC molecules preferentially adsorb onto electrode interface and simultaneously reduce AN diffusion rates through strong intermolecular interactions, leadin...
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Investigation of Electrorheological Fluid Performance with Size‐Controlled TiO2 Nanoparticles
Von Wiley-VCH zur Verfügung gestellt
Diameter of TiO2 particles was controlled ranging from 143 to 370 nm. Size-controlled TiO2 particles were incorporated into electrorheological fluids. Fluids with smaller TiO2 spheres exhibited better electrorheological performance. Smaller TiO2 spheres led to improved dispersion stability in ER fluids.
Electrorheological (ER) fluids, known for their tunable viscosity under electric fields, are of significant interest for various engineering applications, including shock absorbers and haptic feedback systems. This study investigates the impact of size-controlled TiO2 nanoparticles on the performance of ER fluids. TiO2 nanoparticles with diameters ranging from 143 to 370 nm were synthesized using a double-surfactant assembly-directed method. Rheological measurements revealed that ER fluids containing smaller TiO2 particles exhibited higher shear stress under an electric field. Additionally, optical microscopy confirmed that smaller spheres formed denser fibrillar structures, thereby enhancing ER fluid performance. However, dielectric property analysis showed that smaller particles had lower polarizability and slower relaxation. Sedimentation tests indicated that ER fluids with smaller TiO2 particles had improved dispersion stability, further enhancing the performance of the ER fluid. These findings provide valuable insights into optimizing ER fluid performance by controlling TiO2 particle size.
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