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Investigation on the Reaction Mechanism of Methane Oxidation over MgAl2O4‐supported Single‐Atom Catalyst Prepared at High Temperature

Von Wiley-VCH zur Verfügung gestellt

Stability and reactivity of single-atom catalysts (SACs) are the points of concern in catalysis, especially under the harsh conditions, such as at elevated temperatures in oxidizing conditions. Previous work showed that thermally-stable Pt 1 SAC supported on K-modified MgAl 2 O 4 prepared by a vapor-phase self-assembly mechanism (Pt 1 /K/MgAl 2 O 4 ) showed better performance than a Pt/MgAl 2 O 4 nanocatalyst in catalytic CH 4 oxidation ( Chem , 2022, 8, 731-748). However, the detailed reaction mechanism remains unclear, which preventing the further development of single-atom catalysts for CH 4 oxidation. Herein, by means of density functional theory (DFT) calculations, we investigate the sintering resistance behaviour of the Pt 1 /K/MgAl 2 O 4 catalyst, and find that the catalytic CH 4 oxidation takes place via the Mars-van Krevelen (MvK) mechanism, similar to that on conventional oxides. The viewpoint is further verified by experiments. Additionally, other noble metals (Au, Ir and Ru) and alkali elements (Na and Cs) are also investigated and it is found that the alkali types also affect the catalytic performance. This work clarified the reaction mechanism of CH 4 oxidation on metal SAC supported on MgAl 2 O 4 synthesized at high temperature, providing a potent to manipulate the performances of metal SAC in CH 4 oxidation.

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