“My first experiment was a longitudinal observational study on the growth of small fish from a local pond when placed in a plastic cup for a week. Any conclusions were shaky at best due to a lack of rigor in the experimental design … The best ...
Artikel
A Novel Homoconjugated Propellane Triimide: Synthesis, Structural Analyses, and Gas Separation
Von Wiley-VCH zur Verfügung gestellt
A novel homoconjugated propellane comprising three imide groups embedded on a trinaphtho[3.3.3]propellane, has been synthesized and characterized. This rigid propellane triimide is featured with large bathochromic shift, intense luminescence, amplified molar absorptivity, and lower reduction potential relative to the subunits. The propellane triimide readily crystallizes into porous 3D superstructure, which is promising for C2H6/C2H4 separation.
Abstract
Rigid three-dimensional (3D) polycyclic propellanes have garnered interest due to their unique conformational spaces, which display great potential use in selectivity, separation and as models to study through-space electronic interactions. Herein we report the synthesis of a novel rigid propellane, trinaphtho[3.3.3]propellane triimide, which comprises three imide groups embedded on a trinaphtho[3.3.3]propellane. This propellane triimide exhibits large bathochromic shift, amplified molar absorptivity, enhanced fluorescence, and lower reduction potential when compared to the subunits. Computational and experimental studies reveal that the effective through-space π-orbitals interacting (homoconjugation) occurs between the subunits. Single-crystal XRD analysis reveals that the propellane triimide has a highly quasi-D 3h symmetric skeleton and readily crystallizes into different superstructures by changing alkyl chains at the imide positions. In particular, the porous 3D superstructure with S-shaped channels is promising for taking up ethane (C2H6) with very good selectivity over ethylene (C2H4), which can purify C2H4 from C2H6/C2H4 in a single separation step. This work showcases a new class of rare 3D polycyclic propellane with intriguing electronic and supramolecular properties.
Zum VolltextÜberprüfung Ihres Anmeldestatus ...
Wenn Sie ein registrierter Benutzer sind, zeigen wir in Kürze den vollständigen Artikel.