Improved Interface Construction on Anode and Cathode for Na‐Ion Batteries Using Ultralow‐Concentration Electrolyte Containing Dual‐Additives

Electrode/electrolyte interface built by the dual additives of NaDFOB and TMSB enables significant improvement on the cycling stability of hard carbon/NaNi_1/3Fe_1/3Mn_1/3O₂ cell.

Abstract

Compared with Li⁺, Na⁺ with a smaller stokes radius has faster de-solvation kinetics. An electrolyte with ultralow sodium salt (0.3 M NaPF₆) is used to reduce the cell cost. However, the organic-dominated interface, mainly derived from decomposed solvents (SSIP solvation structure), is defective for the long cycling performance of sodium ion batteries. In this work, the simple application of dual additives, including sodium difluoro(oxalato)borate (NaDFOB) and tris(trimethylsilyl)borate (TMSB), is demonstrated to improve the cycling performance of the hard carbon/NaNi_1/3Fe_1/3Mn_1/3O₂ cell by constructing interface films on the anode and cathode. A significant improvement on cycling stability has been achieved by incorporating dual additives of NaDFOB and TMSB. Particularly, the capacity retention increased from 17 % (baseline) to 79 % (w/w, 2.0 wt % NaDFOB) and 83 % (w/w, 2.0 wt % NaDFOB and 1.0 wt % TMSB) after 200 cycles at room temperature. Insight into the mechanism of improved interfacial properties between electrodes and electrolyte in ultralow concentration electrolyte has been investigated through a combination of theoretical computation and experimental techniques.

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