Composite (bi‐)metallic oxides with heterostructure and heteroatom‐doped porous carbon as advanced potassium‐ion battery anodes

A two-step synthesis method is developed to create advanced anode materials for potassium-ion batteries (PIBs). The method combines a metal-organic framework precursor with molecular clusters during thermal conversion, resulting in a composite with unique structural features. The material demonstrates high specific capacity and excellent rate capability, offering superior electrochemical performance for PIBs.

Abstract

In this work, a scalable two-step synthesis method was employed to develop transition metal oxide/carbon composites that exhibit excellent electrochemical performance as the anode of potassium-ion batteries. The functionalized metal-organic framework precursor was combined with molecular silicotungstic acid clusters (SiW9) during thermal conversion, and embedded into in-situ formed porous carbon matrix to form a multi-component CoWO₄/WO₃-C composite material with N-doping. Benefiting from unique compositional and structural features, the resulting composite exhibits an appealing potassium-ion storage performance, such as, large specific capacity of ca. 1500 mAh/g after 600 cycles and excellent rate capability, i. e., delivering reversible capacity over 200 mAh/g even at the high-rate of 2.0 A/g.

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