Recent Developments of Nontraditional Single‐Molecule Toroics

Based on the nontraditional perspective, the exciting advances of SMTs are reviewed ranging from the 3D topological to 1D&2D&3D polymeric SMTs, and 3d–4f to non Dy-based SMTs. The understanding of key design principles and the outlook on nontraditional SMTs will contribute to the design of novel SMTs.

Abstract

Single-molecule toroics (SMTs), defined as a type of molecules with toroidal arrangement of magnetic moment associated with bi-stable non-magnetic ground states, are promising candidates for high-density information storage and the development of molecule based multiferroic materials with linear magneto–electric coupling and multiferroic behavior. The design and synthesis of SMTs by arranging the magnetic anisotropy axis in a circular pattern at the molecular level have been of great interest to scientists for last two decades since the first detection of the SMT behavior in the seminal Dy₃ molecules. Dy^III ion has long been the ideal candidate for constructing SMTs due to its Kramer ion nature as well as high anisotropy. Nevertheless, other Ln^III ions such as Tb^III and Ho^III ions, as well as some paramagnetic transition metal ions, have also been used to construct many nontraditional SMTs. Therefore, we review the progress in the studies of SMTs based on the nontraditional perspective, ranging from the 3D topological to 1D&2D&3D polymeric SMTs, and 3d–4f to non Dy-based SMTs. We hope the understanding we provide about nontraditional SMTs will be helpful in designing novel SMTs.

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