The review involves heterobimetallic catalytic systems that provides access to various organic transformations which are obscure with conventional monometallic systems. It throws light on diverse organic reactions such as alkylation, alkenylation...
Artikel
Photoinduced Copper Catalyzed C(sp2)P Bond Formation by Coupling of Diphenylphosphine with Aryl Iodides
European Journal of Organic Chemistry, September 2025, DOI. Login für Volltextzugriff.
Von Wiley-VCH zur Verfügung gestellt
P Bond Formation by Coupling of Diphenylphosphine with Aryl Iodides"/>
A photoinduced Ullmann-type CP bond-forming reaction is accomplished at room temperature with no additional ligand. This method features broad substrate scope, scalability, and product transformation.
A photoinduced copper-catalyzed coupling of diphenylphosphine with aryl halides is reported. This efficient C(sp2)P bond formation is realized by blue LED irradiation of a copper(I) catalyst at room temperature with no additional ligand. A variety of sterically demanding and functionalized substrates are applied under mild reaction conditions to provide the corresponding triarylphosphines in moderate to good yields.
Zum VolltextÜberprüfung Ihres Anmeldestatus ...
Wenn Sie ein registrierter Benutzer sind, zeigen wir in Kürze den vollständigen Artikel.