Enzyme-ACP complex stability can control substrate preference. Molecular simulations of (top) EcFabG bound to β-ketobutyryl-ACP show salt bridges that are not present when (bottom) PpFabG4 binds to the same substrate. EcFabG is active on a...
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Outside Back Cover: The Importance of Si─ONa─Al Moieties in Fe/ZSM‐5 Zeolite Catalysts for Selective Oxidation of Methane to Acetic Acid
Angewandte Chemie International Edition, September 2025, DOI. Login für Volltextzugriff.
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The image highlights electron transfer from Si─ONa─Al moieties to iron active sites in the Fe/ZSM-5-0.25Na driving selective C─C coupling between methane and CO, efficiently steering the reaction toward acetic acid formation. In their Research Article (e202511056), Jie Zeng, Bo Wu et al. demonstrate a strategy to bypass traditional Brønsted acid dependency, employing metal-electronic modulation to enhance catalytic efficiency, and to establishes an innovative pathway for methane conversion.
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