A silver-catalyzed decarboxylative coupling of readily available oxamic acids with styrenes to the direct synthesis of E-cinnamamides has been developed. The reaction pathway was studied and proven to be different from known procedures.
Artikel
On the Environmentally Friendly Synthesis of 2‐Hydroxyethyl Furan‐5‐Carboxylic Acid (MHEF) and bis(2‐Hydroxyethyl) Furan‐2,5‐Dicarboxylate (BHEF)
ChemistryOpen, September 2025, DOI. Login für Volltextzugriff.
Von Wiley-VCH zur Verfügung gestellt
To better understand how the biocatalyzed depolymerization of polyesters works, model molecules are needed to develop activity assays and determine enzymatic kinetic parameters. In this communication the chemical synthesis and characterization of 2-hydroxyethyl furan-5-carboxylic acid and bis(2-hydroxyethyl) furan-2,5-dicarboxylates as potential model molecules to further study the enzymatic depolymerization of poly(ethylene furanoate) was investigated.
Abstract
To better understand how the biocatalyzed depolymerization of polyesters works, model molecules are needed to develop activity assays and determine enzymatic kinetic parameters. In this communication the chemical synthesis and characterization of 2-hydroxyethyl furan-5-carboxylic acid and bis(2-hydroxyethyl) furan-2,5-dicarboxylates as potential model molecules to further study the enzymatic depolymerization of poly(ethylene furanoate) was investigated.
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