All about halogen-rich electrolytes: The crystal structure, chemical compositions, ion conduction mechanism, synthesis methods, modification strategies, and applications of halogen-rich lithium argyrodite solid-state electrolytes in all-so...
(Localized) Highly Concentrated Electrolytes for Calcium Batteries
Von Wiley-VCH zur Verfügung gestellt
The concept of (localized) highly concentrated electrolytes is for the first time investigated as a way to create calcium conducting electrolytes – much needed as we do not yet have a standard electrolyte readily plating and stripping calcium. From this stepping-stone we may eventually unlock the potential in synergetic development of local and global structure and dynamics for electrolytes.
The concept of non-aqueous highly concentrated electrolytes (HCEs) for modern rechargeable batteries has recently evolved further by also adding a non-coordinating solvent, i. e., a diluent, to create localized HCEs (LHCEs). LHCEs rely on a charge carrier design similar to that of HCEs in synergy with tailored macroscopic properties, especially reduced viscosity. LHCEs have now been extensively investigated for monovalent Li+ and Na+ based batteries, but here we investigate both HCEs and LHCEs for divalent Ca2+ conducting systems. Here we systematically map both molecular and macroscopic features as function of composition of Ca(TFSI)2 (calcium bis(trifluoromethane)sulfonimide) in PC (propylene carbonate) based HCEs as well as the corresponding LHCEs created using TTE (1,1,2,2-tetrafluoroethyl-2,2,3,3-tetrafluoropropyl ether) as diluent. Some unique HCE properties arise already at ca. 2.00 m, which is at a lower salt concentration than for monovalent systems, and in addition the local structure of the HCE can be maintained even within a nominal 0.45 m LHCE (starting from a 3.26 m parent HCE). The combined observations made at molecular and macro levels pave the way for further optimization of important physico-chemical properties, proper design of electrochemical investigations, and eventually a better understanding of how to best improve the desolvation kinetics at e. g., the electrolyte/electrode interfaces of a Ca metal anode.Zum Volltext
Jetzt nächsten Artikel lesen:
Überprüfung Ihres Anmeldestatus ...
Wenn Sie ein registrierter Benutzer sind, zeigen wir in Kürze den vollständigen Artikel.