“A carbodiimide-fueled approach is demonstrated to instruct the self-assembly of π-conjugated peptides and be responsive to thermal disassembly cues upon consumption of the assembly trigger. The carbodiimide-fueled assembly processes can be modul...
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Influence of Silicate Rock Glass Compositions on the Efficacy of Prebiotic RNA Polymerization Reactions: The Case of 3’,5’ Cyclic Guanosine Monophosphate
Von Wiley-VCH zur Verfügung gestellt
Silicate glasses are ubiquitous on terrestrial planets wherever molten rock – generated by volcanism or impacts – is quenched by air or water. Hence, they provided ready and abundant reactive solid surfaces for prebiotic chemistry on the early Earth. Here, we show that rock glass composition determines basicity, which in turn modulates the outcome of prebiotic synthetic processes such as the polymerization of 3’,5’ cyclic guanosine monophosphate.
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