Transition metal doped Ni2P has been prepared by a solvent-less pyrolysis route employing [Ni{S2P(OH)(4-CH3OC6H4)}2], [Fe{S2P(OH)(4-CH3OC6H4
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Hydrogenation of Olefins Catalyzed by a Cobalt(I) Hydride Complex with N‐Heterocyclic Silylene
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Herein, cobalt(I) complexes with a monodentate N-heterocyclic imino substituted silylene were synthesized and characterized. The cobalt(I) hydride complex 3 exhibits high catalytic efficiency in the hydrogenation of olefins with good chemoselectivity and functional group compatibility.
Abstract
Herein, we report the synthesis, characterization, and reactivity of the cobalt(I) complexes with an N-heterocyclic imino substituted silylene. The cobalt(I) hydride complex exhibits high catalytic efficiency and chemoselectivity as well as good functional group compatibility in the hydrogenation of olefins.
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