A novel ZIF-assisted strategy was developed to synthesize Co nanoparticles loaded on mesoporous N-doped carbon support of hollow cubic nanobox constructed by pyrolysis of TA-treated ZIF-67 at high temperature. The Co−NC-800 NBs-based ZABs ...
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Highly Regioselective Synthesis of N‐β‐trifluoromethyl 2‐pyridones via anti‐Markovnikov Hydroamination of α‐(trifluoromethyl)styrenes with 2‐pyridones
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A novel and facile method for the synthesis of N-β-CF3-substituted 2-pyridones via hydroamination of α-(trifluoromethyl)styrenes with 2-pyridones was described. The reaction proceeded smoothly at room temperature, affording a variety of N-(β-trifluoromethyl-β-arylethyl)pyridin-2(1H)-ones in moderate to good yields with excellent N-regioselectivity.
Abstract
A novel and facile method for the synthesis of N-β-CF3-substituted 2-pyridones via hydroamination of α-(trifluoromethyl)styrenes with 2-pyridones was described. The reaction proceeded smoothly at room temperature, affording a variety of N-(β-trifluoromethyl-β-arylethyl)pyridin-2(1H)-ones in moderate to good yields with excellent N-regioselectivity.
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