Highly Active Hydrogen‐rich Photothermal Reverse Water Gas Shift Reaction on Ni/LaInO3 Perovskite Catalysts with Near‐unity Selectivity

Ni/LaInO₃ was designed to obtain an efficient photothermal CO₂ conversion with a high CO yield rate (1314 mmol g_Ni ⁻¹ h⁻¹) and ≈100 % selectivity, where LaInO₃ was enriched extensive oxygen vacancies to roundly adsorbing CO₂ and the strong interaction with Ni endowed the catalysts with powerful H₂ activity. In situ characterizations demonstrated a COOH* pathway and the photoinduced charge transfer process to reduce the reaction active energy.

Abstract

Photo-assisted reverse water gas shift (RWGS) reaction is regarded green and promising in controlling the reaction gas ratio in Fischer Tropsch synthesis. But it is inclined to produce more byproducts in high H₂ concentration condition. Herein, LaInO₃ loaded with Ni-nanoparticles (Ni NPs) was designed to obtain an efficient photothermal RWGS reaction rate, where LaInO₃ was enriched with oxygen vacancies to roundly adsorbing CO₂ and the strong interaction with Ni NPs endowed the catalysts with powerful H₂ activity. The optimized catalyst performed a large CO yield rate (1314 mmol g_Ni ⁻¹ h⁻¹) and ≈100 % selectivity. In situ characterizations demonstrated a COOH* pathway of the reaction and photoinduced charge transfer process for reducing the RWGS reaction active energy. Our work provides valuable insights on the construction of catalysts concerning products selectivity and photoelectronic activating mechanism on CO₂ hydrogenation.

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