The cover illustrates the chiral self-sorting and adaptive host-guest behavior of flex-COP-n, a new family of flexible covalent organic pillars with deep-cavity architectures (<a target="_blank"
 title="Link to external resource"
 href="https://doi.org/10.1002/anie.202509177">e202509177</a>). These nanotubular hosts form enantiomeric or meso duplexes via dynamic imine condensation and accommodate guest molecules through mutual deformation. Cartoon springs and character-filled cavities depict how host and guest adjust their shapes to achieve precise molecular recognition, echoing biological receptors.

Artikel

Frontispiece: Chiral Self‐Sorting of Flexible Covalent Organic Pillars for Adaptive Molecular Recognition

The cover illustrates the chiral self-sorting and adaptive host-guest behavior of flex-COP-n, a new family of flexible covalent organic pillars with deep-cavity architectures (e202509177). These nanotubular hosts form enantiomeric or meso duplexes via dynamic imine condensation and accommodate gu...

Using electrochemistry to enact organic molecule transformations offers a potential route towards greener chemical manufacturing. However, such reactions can often be complex with a multitude of factors at play. In their Communication (<a target="_blank"
 title="Link to external resource"
 href="https://doi.org/10.1002/anie.202509115">e202509115</a>), Yanwei Lum et al. performed a systematic study of the impact of electrolyte cations on the selectivity of electrochemical C─H chlorination of cyclohexane. It was found that larger cations increase the propensity towards the formation of chlorine radicals, which then facilitates the formation of chlorocyclohexane through a radical non-chain mechanism.

Artikel

Frontispiece: Chiral Self‐Sorting of Flexible Covalent Organic Pillars for Adaptive Molecular Recognition

Jetzt nächsten Artikel lesen:

Seite 1

Frontispiece: Alkali Metal Cations Impact the Selectivity of Radical‐Mediated Electrochemical C─H Chlorination

Überprüfung Ihres Anmeldestatus ...