The cover picture illustrates a novel data-driven approach to the hydrogenation of CO2, providing unprecedented opportunities to enhance catalyst design and to optimize reactions. This innovative data-driven approach excels at identifying hidden descriptors and evaluating quantitative structure-activity relationship (QSAR), enabling the rapid prediction of catalytic performance. More details can be found in article number <a href="https://doi.org/10.1002/asia.202500512">202500512</a> by Guangchao Liang and co-workers.

Artikel

Front Cover: Boosting Homogeneous Hydrogenation of CO2 via the Data‐Driven Approach (Chem. Asian J. 16/2025)

The cover picture illustrates a novel data-driven approach to the hydrogenation of CO2, providing unprecedented opportunities to enhance catalyst design and to optimize reactions. This innovative data-driven approach excels at identifying hidden descriptors and evaluating quantitative structure-a...

Organotetrel compounds are important reagents with broad applications in chemical industries and natural product synthesis. This review provides a summary of strategies for the synthesis of propargylic and allenic organotetrels in their enantioenriched forms. It details strategies of stereoinduction, features and scope of synthetic approaches, and mechanistic insights into key transformations.


 
<h2>Abstract</h2>
Enantioenriched propargylic and allenic derivatives of silicon, germanium, and tin are versatile building blocks for stereoselective synthesis. Consequently, considerable efforts toward their efficient and selective synthesis have been made, both through classical approaches for chirality transfer and catalytic enantioselective strategies that employ the latest developments in transition metal catalysis, organocatalysis, and photoredox catalysis. In this review, we survey broadly applicable synthetic strategies and discuss the scope and mechanistic details for specific protocols that afford these compounds in a regio- and stereoselective manner.

Artikel

Front Cover: Boosting Homogeneous Hydrogenation of CO2 via the Data‐Driven Approach (Chem. Asian J. 16/2025)

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Asymmetric Synthesis of Propargylic and Allenic Silanes, Germanes, and Stannanes

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