A DNA-based dissipation system with synchronized multiple molecular fuels provides multiple transient states and enhanced complexity. The dissipation system is harnessed to dynamically regulate the assembly of DNA nanotubes allowing for co...
Dinuclear Mn(I) Complexes with Phosphido and Hydrido Bridges: Synthesis, Reactivity, and Hydrogenative Catalysis
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The simple class of dinuclear Mn(I) carbonyl compounds with phosphido (PR2 −) and hydrido (H−) bridges has been known since the 1960’s. Only recently were they discovered to have potential catalytic applications. This Review is a fresh look the synthesis, reactivity, and catalysis of this interesting class of molecules.
A class of organomanganese hydrogenation catalysts was recently rediscovered. These are simple dinuclear Mn(I) carbonyl compounds with phosphido (PR2 −) and hydrido (H−) bridges. This class of compounds has been known since the 1960’s, and they have rich coordination chemistry and reactivity. Given their recently discovered potential for catalytic applications, a fresh look at this class of compounds was necessary. Hence, this Review comprehensively covers the synthesis, reactivity, and catalysis of this interesting class of molecules.Zum Volltext
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