A flash monitoring approach led to the direct observation of reactive intermediates in anionic polymerization. By using flow microreactors and in-line spectroscopic devices, the living ends of anionic polymerization could be analyzed by FT...
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Cover Feature: Enantioselective Total Synthesis of the Morphogen (−)‐Thallusin and Mediated Uptake of Fe(III) into the Green Seaweed Ulva (Chem. Eur. J. 18/2024)
Chemistry – A European Journal, März 2024, DOI. Login für Volltextzugriff.
Von Wiley-VCH zur Verfügung gestellt
The algal morphogen (−)-thallusin was stereoselectively synthesized by implementing an IrI-catalyzed enantioselective polyene cyclization. A TMS group tracelessly directed the regioselectivity. (−)-Thallusin is secreted by bacteria associated with the green seaweed Ulva and forms a stable 2:1 FeIII complex that the algae take up, selectively promoting their massive development. More information can be found in the Research Article by T. Wichard. H.-D. Arndt and co-workers (DOI: 10.1002/chem.202304007). Background picture: Seaphotoart/Alamy Stock Foto.
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