21 vanadium bis-phenolate benzimidazolyidene complexes spanning three oxidation states have been investigated. Special emphasis is thereby laid on their salt metathesis reactivity and the accessibility of the +IV oxidation state by reductive or o...
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Catalysis for Oleochemical Platforms
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This reviews article illustrates the most recent advances in the catalytic treatment of biomasses derived from vegetable oils, made at the University of Naples Federico II, dealing with: (i) biodiesel production; (ii) esterification to obtain high-added value products; (iii) epoxidation of vegetable oils; (iv) glycerol ketalization; (v) oxidative cleavage of unsaturated fatty acids.
Abstract
The present review articles the most recent efforts, made in the Department of Chemical Sciences of the University of Naples Federico II, in the catalytic treatment of biomasses derived from vegetable oils. The review is focused on several technologies aimed at the production of either biofuels or valuable chemicals: (i) biodiesel production; (ii) esterification to obtain high-added value products; (iii) epoxidation of vegetable oils; (iv) glycerol ketalization; (v) oxidative cleavage of unsaturated fatty acids. The results are critically summarized to highlight the scientific activities and the main results in the field of biorefinery concept.
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