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A Tetrahedral Bisacridine Donor Enables Fast Radiative Decay in Thermally Activated Delayed Fluorescence Emitter

Achieving high efficiency and low efficiency roll-off simultaneously is of great significance for further application of thermally activated delayed fluorescent (TADF) emitters. A balance between radiative decay and reversed intersystem crossing must be carefully established. Herein, we propose a qunolino-acridine (QAc) donor composing two acridine with both planar (pAc) and bended (bAc) geometries. Combining with triazine, a TADF emitter QAc-TRZ is assembled. The pAc provides a well interaction with triazine which ensures a decent TADF behavior, while the bAc offers a delocalization of highest occupied molecular orbital (HOMO) which guarantees an enhancement of radiative decay. Remarkably, QAc-TRZ enables a highly efficient organic light emitting diode (OLED) with maximum external quantum efficiency (EQE) of 37.3%. More importantly, the efficiencies under 100/1000 cd/m2 stay 36.3% and 31.7%, respectively, and remain 21.5% even under 10000 cd/m2.

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