Introducing organic groups into metal silicate catalysts and thus supposedly changing the surface hydrophobicity has been shown to enhance the catalyst performance in various reactions. However, the organic groups introduction does not unambiguous...
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1,2‐Arylsulfonylation of Vinyl Ethers and Esters Enabled by Dual Ni Catalysis
Von Wiley-VCH zur Verfügung gestellt
A dual photocatalytic sulfonylation-arylation of electron-rich alkenes is described. By combining sulfinate salts, (hetero)-aryl-bromides and 2,3-dihydrofuran under Ru and Ni dual catalysis, over 35 examples of aryl-sulfonylated scaffolds could be obtained in good to excellent yields, under mild reaction conditions and high diastereoselectivity.
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