PtNi/Sb0.11SnO2 with high durability was synthesized by adjusting the doping amount of antimony. The prepared PtNi/Sb0.11SnO2 retained excellent catalytic activity and hardly reduced half-wave potential...
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Triphenylamine‐Based N,O‐Bidentate BF2‐Enolimine Initiator for Three‐Arm Star Polymethacrylates with Dual‐State Fluorescent Emission
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Three-arm star polymethacrylates with dual-phase (solution and solid-state) fluorescent emission were synthesized via ATRP using a triphenylamine-derived organoboron complex TAPA-BKI-3Br as initiator.
Abstract
Three-arm star polymethacrylates with dual-phase (solution and solid-state) fluorescent emission have been synthesized via atom transfer radical polymerization (ATRP) using a triphenylamine-derived organboron complex (TAPA-BKI-3Br) as initiator. The as-synthesized three-arm star polymethacrylates exhibited bright emission in both solution and the solid states due to the highly twisted structure and intramolecular charge transfer (ICT) effect of TAPA-BKI core, as well as the steric effect and restriction of intramolecular motions from the polymer arms. And the polymer chains have an important influence on the photophysical behavior of the as-synthesized three-arm star polymethacrylates in the aggregated state.
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