A self-promoted glycosylation method for the stereoselective formation of β-glucosides from a substrate library of glycosyl trichloroacetimidate glycosyl donors and glycosyl acceptors is presented. The simple two-component reaction takes place at ...
Artikel
Synthesis and Reactivity of Dithienopyrazines
Von Wiley-VCH zur Verfügung gestellt
The efficient preparation and investigation of so far unknown heterotriacenes, basic anti- and syn-dithienopyrazine 5 and 6 is reported. The comparison of the two isomers with respect to electronic properties and follow-up reactions gives insights into structure-property and -reactivity relationships. Examples of transition metal-catalyzed C−C cross-coupling reactions of corresponding halogenated derivatives show the practical impact for extended π-conjugated systems applied in optoelectronic devices.
Abstract
Heteroacenes developed to widely used building blocks in organic semiconductors for application in organic electronics due to their tunable structures and properties concomitant with inherent stability. Here, we report efficient preparation and investigation of so far unknown heterotriacenes, basic anti- and syn-dithienopyrazine 5 and 6. The comparison of the two isomers with respect to electronic properties and follow-up reactions gives insights into structure-property and -reactivity relationships. Examples of transition metal-catalyzed C−C cross-coupling reactions of corresponding halogenated derivatives show the practical impact for extended π-conjugated systems applied in optoelectronic devices.
Zum VolltextÜberprüfung Ihres Anmeldestatus ...
Wenn Sie ein registrierter Benutzer sind, zeigen wir in Kürze den vollständigen Artikel.