Photocatalytic Water Splitting Driven by Surface Plasmon Resonance

Surface plasmon resonance (SPR) in metals possesses unique optical properties and photoelectric functions, which are helpful for light harvesting in photocatalysis. Additionally, the plasmon-associated charge transfer process gives a complementary platform to understand the charge dynamics at a fundamental level. This review focused on the recent developments of water splitting by plasmonic metals/semiconductors photocatalysts. Firstly, the basic characteristics of SPR and the plasmon-enhanced photocatalysis mechanisms including plasmon resonance energy transfer and interfacial charge transfer are introduced, highlighting the recent cognition of the plasmonic electron-hole separation, distribution, and the reaction sites for water splitting. Then, advances in the strategies to improve the quantum efficiency of plasmon-induced water splitting are summarized from the aspects of modulation in metals, interface contacts, and bulk properties of semiconductors. Finally, we raised several prospects in developing high-efficient plasmonic metals/semiconductors photocatalysts for water splitting.