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Deoxygenative Radical Boration of Inert Amides via a Combination of Relay and Cooperative Catalysis

Von Wiley-VCH zur Verfügung gestellt

The boryl radical generated in situ is used as a type of reactive functionalization agent instead of traditional nucleophiles… thus effectively overcoming the limitation of C-based functionalization reagents to deliver highly valuable α-boryl amines from amides.” This and more about the story behind the front cover can be found in the article at 10.1002/chem.202301199).


Invited for the cover of this issue is the group of Prof. Xiaoming Wang at the Shanghai Institute of Organic Chemistry and Hangzhou Institute for Advanced Study, University of the Chinese Academy of Sciences. The image depicts a combination of relay and cooperative catalysis with a triple iridium–photoredox–organocatalysis system to achieve an unprecedented reductive boration of amides. Read the full text of the article at 10.1002/chem.202301199.

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