Unraveling the complicated photophysics of thermally activated delayed fluorescence (TADF) compounds is not a trivial task, although it is critical to improve the performance of TADF emitters in OLED. In the Review by Zhao and colleagues (DOI:
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Cover Feature: Asymmetrical Platinum and Rhodium Dinuclear Complex Strongly Bound to Filled d Complexes by Unbridged Pt−Metal Bonds: Toward Heterometallic‐Extended Metal Atom Chains (Chem. Eur. J. 16/2023)
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Heterometallic trinuclear or pentanuclear complexes aligned as Rh−Pt−M or Rh−Pt−M−Pt−Rh (M=Pt, Pd, Cu), respectively, were kinetically and thermodynamically synthesized and characterized. These polynuclear complexes, in which three kinds of metals form straight one-dimensional structures with metal–metal bonds, are presented as sweet, three-colored, Japanese dango dumplings. More information can be found in the Research Article by K. Uemura and co-workers (DOI: 10.1002/chem.202204057).
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