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Carpet beater molecules: synthesis and characterization of functional of hexa‐peri‐benzocoronene‐alkyne coupling products

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Within the scope of this paper nine p-expanded mono-substituted 5,8,11,14,17-pentakis-(tert-butyl)-hexa-peri-hexabenzo-coronenes (HBC) are introduced. 2-Iodo-5,8,11,14,17-pentakis-(tert-butyl)-hexa-peri-hexabenzocoronene served as precursor and was reacted with ethynyltrimethylsilane in a Sonogashira coupling reaction. The acetylene unit is used as a linker and can undergo another Sonogashira coupling reaction combining different phenyl coupling partners with the HBC core. The electron-withdrawing groups such as nitrile, pyridine and carbonyl species (aldehyde, methylester, carbonic acid) as well as the three quinoxaline based species (diphenylquinoxaline, dibenzop[a,c]phenazine, phenanthrol[4’,5’-a,b,c]phenazine) serve as substitution moieties. Their influence on the optoelectronic properties were investigated via UV/Vis absorption spectroscopy demonstrating a maximum redshift of 7 nm compared to starting compound HBC-I. As for the phenanthrol[4’,5’-a,b,c]phenazine substituted HBC a dramatic decrease in the intensity of the absorption of the UV/Vis spectrum was observed. The fluorescence spectroscopy pointed out that the dibenzo[a,c]phenazine and phenanthrol[4’,5’-a,b,c]phenazine substitution changed the spectra to one broad peak departing from the characteristic HBC-like emission pattern.

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